Concept explainers
Predict the relative pH (greater than
a. Sodium hypochlorite,
b. Sodium formate,
c. Potassium nitrate,
d. Sodium phosphate,
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Chemistry for Today: General, Organic, and Biochemistry
- What is a salt? List some anions that behave as weak bases in water. List some anions that have no basic properties in water. List some cations that behave as weak acids in water. List some cations that have no acidic properties in water. Using these lists, give some formulas for salts that have only weak base properties in water. What strategy would you use to solve for the pH of these basic salt solutions? Identify some salts that have only weak acid properties in water. What strategy would you use to solve for the pH of these acidic salt solutions? Identify some salts that have no acidic or basic properties in water (produce neutral solutions). When a salt contains both a weak acid ion and a weak base ion, how do you predict whether the solution pH is acidic, basic, or neutral?arrow_forward. A buffered solution is prepared containing acetic acid, HC2H3O2, and sodium acetate, NaC2H3O2, both at 0.5 M. Write a chemical equation showing how this buffered solution would resist a decrease in its pH if a few drops of aqueous strong acid HCI solution were added to it. Write a chemical equation showing how this buffered solution would resist an increase in its pH if a few drops of aqueous strong base NaOH solution were added to it.arrow_forwardCalculate the mass of sodium hydroxide that must be added to 1.00 L of 1.00-M HC2H3O2 to double the pH of the solution (assume that the added NaOH does not change the volume of the solution).arrow_forward
- Calculate the pH of each of the following solutions. (a) 10.0 mL of 0.300 M hydrofluoric acid plus 30.0 mL of 0.100 M sodium hydroxide (b) 100.0 mL of 0.250 M ammonia plus 50.0 mL of 0.100 M hydrochloric acid (c) 25.0 mL of 0.200 M sulfuric acid plus 50.0 mL of 0.400 M sodium hydroxidearrow_forwardConsider all acid-base indicators discussed in this chapter. Which of these indicators would be suitable for the titration of each of these? (a) NaOH with HClO4 (b) acetic acid with KOH (c) NH3 solution with HBr (d) KOH with HNO3 Explain your choices.arrow_forwardTwo strategies are also followed when solving for the pH of a base in water. What is the strategy for calculating the pH of a strong base in water? List the strong bases mentioned in the text that should be committed to memory. Why is calculating the pH of Ca(OH)2 solutions a little more difficult than calculating the pH of NaOH solutions? Most bases are weak bases. The presence of what element most commonly results in basic properties for an organic compound? What is present on this element in compounds that allows it to accept a proton? Table 13-3 and Appendix 5 of the text list Kb values for some weak bases. What strategy is used to solve for the pH of a weak base in water? What assumptions are made when solving for the pH of weak base solutions? If the 5% rule fails, how do you calculate the pH of a weak base in water?arrow_forward
- Use the same symbols as in Question 61 ( = anion, =OH) for the box below. (a) Fill in a similar box (representing one liter of the same solution) after 2 mol of H+ (2) have been added. Indicate whether the resulting solution is an acid, base, or buffer. (b) Follow the directions of part (a) for the resulting solution after 2 mol of OH- (2 ) have been added. (c) Follow the directions of part (a) for the resulting solution after 5 mol of OH- (5 ) have been added. (Hint: Write the equation for the reaction before you draw the results.)arrow_forwardComposition diagrams, commonly known as alpha plots, are often used to visualize the species in a solution of an acid or base as the pH is varied. The diagram for 0.100 M acetic acid is shown here. The plot shows how the fraction [alpha ()] of acetic acid in solution, =[CH3CO2H][CH3CO2H]+[CH3CO2] changes as the pH increases (blue curve). (The red curve shows how the fraction of acetate ion, CH3CO2, changes as the pH increases.) Alpha plots are another way of viewing the relative concentrations of acetic acid and acetate ion as a strong base is added to a solution of acetic acid in the course of a titration. (a) Explain why the fraction of acetic acid declines and that of acetate ion increases as the pH increases. (b) Which species predominates at a pH of 4, acetic acid or acetate ion? What is the situation at a pH of 6? (c) Consider the point where the two lines cross. The fraction of acetic acid in the solution is 0.5, and so is that of acetate ion. That is, the solution is half acid and half conjugate base; their concentrations are equal. At this point, the graph shows the pH is 4.74. Explain why the pH at this point is 4 74.arrow_forward1. Benzoic acid is often an active ingredient in acne and skin cream. Calculate the pH and pOH of a 0.15 M benzoic acid solution. 2. Aniline is widely used in the dye and polymer industries. Calculate the pH and pOH of a 4.5 M aniline solution. 3. Commercial ammonia generally has a mass percent concentration of 25% NH3, which translates to 14.7 M NH3. Calculate the pH and pOH of a quarter strength ammonia solution.arrow_forward
- Dissolve 5.00 g sodium-hydroxide in water and take out 10 cm3 from this solution, thendilute it to 500 cm3. The pH of this diluted solution is 12.0. What is the volume and theconcentration of the original solution?MM[NaOH] = 40 g/molarrow_forwardCalculate the pH of each of the following strong acid solutions. A. 5.55×10−2 M HNO3. Express the pH of the solution to three decimal places. B. 0.260 gg of HClO3 in 2.70 L of solution. Express the pH of the solution to three decimal places. C. 5.00 mL of 2.00 M HCl diluted to 0.500 L . Express the pH of the solution to three decimal places. D. A mixture formed by adding 40.0 mL of 2.5×10−2 M HCl to 120 mL of 1.0×10−2 M HI. Express the pH of the solution to two decimal places.arrow_forwardOver the past 250 years, the average upper-ocean pH near the Pacific Northwest has decreased by about 0.1 units, from about 8.2 to 8.1. This drop in pH corresponds to an increase in acidity of about 30%. When CO2 levels in seawater rise, the availability of carbonate ion, CO32−, makes it more difficult for marine organisms to build and maintain shells and other body parts from calcium carbonate. Calculate H3O+ and OH− concentrations at pH levels of 8.2 and 8.1. Demonstrate by calculations that this decrease in pH corresponds to an increase in acidity of about 30%. Explain the relationship between the pH of seawater and the availability of carbonate ions. Does the change in pH from 8.2 to 8.1 result in an increase or decrease in the availability of carbonate ions?arrow_forward
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