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General Chemistry - Standalone boo...

11th Edition
Steven D. Gammon + 7 others
ISBN: 9781305580343

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BuyFindarrow_forward

General Chemistry - Standalone boo...

11th Edition
Steven D. Gammon + 7 others
ISBN: 9781305580343
Textbook Problem

Using Mulliken’s formula, calculate a value for the electronegativity of oxygen. Convert the result to a value on Pauling’s scale. See Problem 9.149.

Interpretation Introduction

Interpretation:

The electronegativity of Oxygen, the value of result is converted to Pauling’s scale has to be calculated.

Concept introduction:

Pauling’s scale is based on an empirical relation among the energy of a bond and the electronegativities of bonded atoms.

EA-B>EA-A×EB-B

Mullikan’s Scale:

According to this method electronegativity could be regarded as the average of the ionization energy and electron affinity of an atom

Electronegativity=I.E+E.A2

Explanation

The electronegativity of Oxygen is calculated

X=I.E+E.A2=[1314+141]kJ/mol2=727_.5kJ/mol

725

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