Organic Chemistry, 2nd Edition (wileypl...2nd EditionDavid Klein Publisher: WILEYISBN: 9781118795712
Organic Chemistry, 2nd Edition (wileypl...
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Chapter 1 - A Review Of General Chemistry: Electrons, Bonds, And Molecular PropertiesChapter 1.2 - The Structural Theory Of MatterChapter 1.3 - Electrons, Bonds, And Lewis StructuresChapter 1.4 - Identifying Formal ChargesChapter 1.5 - Induction And Polar Covalent BondsChapter 1.6 - Atomic OrbitalsChapter 1.9 - Hybridized Atomic OrbitalsChapter 1.10 - Vsepr Theory: Predicting GeometryChapter 1.11 - Dipole Moments And Molecular PolarityChapter 1.12 - Intermolecular Forces And Physical Properties
Chapter 2 - Molecular RepresentationsChapter 2.1 - Molecular RepresentationsChapter 2.2 - Bond-line StructuresChapter 2.3 - Identifying Functional GroupsChapter 2.4 - Carbon Atoms With Formal ChargesChapter 2.5 - Identifying Lone PairsChapter 2.6 - Three-dimensional Bond-line StructuresChapter 2.8 - Curved ArrowsChapter 2.9 - Formal Charges In Resonance StructuresChapter 2.10 - Drawing Resonance Structures Via Pattern RecognitionChapter 2.11 - Assessing Relative Importance Of Resonance StructuresChapter 2.12 - Delocalized And Localized Lone PairsChapter 3 - Acids And BasesChapter 3.2 - Flow Of Electron Density: Curved Arrow NotationChapter 3.3 - Bronsted-lowry Acidity: A Quantitative PerspectiveChapter 3.4 - Bronsted-lowry Acidity: Qualitative PerspectiveChapter 3.5 - Position Of Equilibrium And Choice Of ReagentsChapter 3.7 - Solvating EffectsChapter 3.9 - Lewis Acids And BasesChapter 4 - Alkanes And CycloalkanesChapter 4.2 - Nomenclature Of AlkanesChapter 4.3 - Constitutional Isomers Of AlkanesChapter 4.6 - Drawing Newman ProjectionsChapter 4.7 - Conformational Analysis Of And VropaneChapter 4.8 - Conformational Analysis Of ButaneChapter 4.11 - Drawing Chair ConformationsChapter 4.12 - Monusubstituted CyclohexaneChapter 4.14 - Cis-trans StereoisomerismChapter 5 - StereoisomerismChapter 5.1 - Overview Of IsomerismChapter 5.2 - Introduction To StereoisomerismChapter 5.3 - Designating Configuration Using The Cahn-ingold-prelog SystemChapter 5.4 - Optical ActivityChapter 5.5 - Stereoisomeric Relationships: Enantiomers And DiastereomersChapter 5.6 - Symmetry And ChiralityChapter 5.7 - Fischer ProjectionsChapter 6 - Chemical Reactivity And MechanismsChapter 6.1 - EnthalpyChapter 6.2 - EntropyChapter 6.3 - Gibbs Free EnergyChapter 6.4 - EquilibriaChapter 6.6 - Reading Energy DiagramsChapter 6.7 - Nucleophiles And ElectrophilesChapter 6.8 - Mechanisms And Arrow PushingChapter 6.9 - Combining The Patterns Of Arrow PushingChapter 6.10 - Drawing Curved ArrowsChapter 6.11 - Carbocation RearrangementsChapter 7 - Substitution ReactionsChapter 7.2 - Alkyl HalidesChapter 7.3 - Possible Mechanisms For Substitution ReactionsChapter 7.4 - The Sn2 MechanismChapter 7.5 - The Sn1 MechanismChapter 7.6 - Drawing The Complete Mechanism Of An Sn1 ReactionChapter 7.7 - Drawing The Complete Mechanism Of An Sn2 ReactionChapter 7.8 - Determining Which Mechanism PredominatesChapter 7.9 - Selecting Reagents To Accomplish Functional Group TransformationChapter 8 - Alkenes: Structure And Preparation Via Elimination ReactionsChapter 8.3 - Nomenclature Of AlkenesChapter 8.4 - Stereoisomerism In AlkenesChapter 8.5 - Alkene StabilityChapter 8.6 - Possible Mechanisms For EliminatlonChapter 8.7 - The E2 MechanismChapter 8.8 - Drawing The Products Of An E2 ReactionChapter 8.9 - The E1 MechanismChapter 8.10 - Drawing The Complete Mechanism Of An E1 ProcessChapter 8.11 - Drawing The Complete Mechanism Of An E2 ProcessChapter 8.12 - Substitution Vs. Elimination: Identifying The ReagentChapter 8.13 - Substitution Vs. Elimination: Identifying The Mechanism(s)Chapter 8.14 - Substitution Vs. Elimination: Predicting The ProductsChapter 9 - Addition Reactions Of AlkenesChapter 9.3 - HydrohalogenationChapter 9.4 - Acid-catalyzed HydrationChapter 9.6 - Hydroboration-oxidationChapter 9.7 - Catalytic HydrogenationChapter 9.8 - Halogenation And Halohydrin FormationChapter 9.9 - Anti DihydroxylationChapter 9.10 - Syn DihydroxylationChapter 9.11 - Oxidative OeavageChapter 9.12 - Predicting Products Of An Addition ReactionChapter 9.13 - Synthesis StrategiesChapter 10 - AlkynesChapter 10.2 - Nomenclature Of AlkynesChapter 10.3 - Acidity Of Acetylene And Terminal AlkynesChapter 10.4 - Preparing AlkynesChapter 10.5 - Reduction Of AlkynesChapter 10.6 - Hydrohalogenation Of AlkynesChapter 10.7 - Hydration Of AlkynesChapter 10.9 - Ozonolysis Of AlkynesChapter 10.10 - Alkylation Of Terminal AlkynesChapter 10.11 - Synthesis StrategiesChapter 11 - Radical ReactionsChapter 11.1 - RadicalsChapter 11.2 - Common Patterns In Radical MechanismsChapter 11.3 - Chlorination Of MethaneChapter 11.5 - Selectivity Of HalogenationChapter 11.6 - Stereochemistry Of HalogenationChapter 11.7 - Allylic BrominationChapter 11.8 - Atmospheric Chemistry And The Ozone LayerChapter 11.9 - Autooxidation And AntioxidantsChapter 11.10 - Radical Addition Of Hbr: Anti-markovnikov AdditionChapter 12 - SynthesisChapter 12.1 - One-step SynthesesChapter 12.2 - Functional Group TransformationsChapter 12.3 - Reactions That Change The Carbon SkeletonChapter 12.4 - How To Approach A Synthesis ProblemChapter 12.5 - Retrosynthetic AnalysisChapter 13 - Alcohols And PhenolsChapter 13.1 - Structure And Properties Of AlcoholsChapter 13.2 - Acidity Of Alcohols And PhenolsChapter 13.3 - Preparation Of Alcohols Via Substitution Or AdditionChapter 13.4 - Preparation Of Alcohols Via ReductionChapter 13.6 - Preparation Of Alcohols Via Grignard ReagentsChapter 13.7 - Protection Of AlcoholsChapter 13.9 - Reactions Of Alcohols: Substitution And EliminationChapter 13.10 - Reactions Of Alcohols: OxidationChapter 13.13 - Synthesis StrategiesChapter 14 - Ethers And Epoxides; Thiols And SulfidesChapter 14.2 - Nomenclature Of EthersChapter 14.4 - Crown EthersChapter 14.5 - Preparation Of EthersChapter 14.6 - Reactions Of EthersChapter 14.7 - Nomenclature Of EpoxidesChapter 14.8 - Preparation Of EpoxidesChapter 14.9 - Enantioselective EpoxidationChapter 14.10 - Ring-opening Reactions Of EpoxidesChapter 14.11 - Thiols And SulfidesChapter 14.12 - Synthesis Strategies Involving EpoxidesChapter 15 - Infrared Spectroscopy And Mass SpectrometryChapter 15.3 - Signal Characteristics: WavenumberChapter 15.4 - Signal Characteristics: IntensityChapter 15.5 - Signal Characteristics: ShapeChapter 15.6 - Analyzing An Ir SpectrumChapter 15.7 - Using Ir Spectroscopy To Distinguish Between Two CompoundsChapter 15.9 - Analyzing The (m)+· PeakChapter 15.10 - Analyzing The (m+1)+· PeakChapter 15.11 - Analyzing The (m+2)+· PeakChapter 15.12 - Analyzing The FragmentsChapter 15.13 - High Resolution Mass SpectrometryChapter 15.16 - Hydrogen Deficiency Index: Degrees Of UnsaturationChapter 16 - Nuclear Magnetic Resonance SpectroscopyChapter 16.4 - Number Of SignalsChapter 16.5 - Chemical ShiftChapter 16.6 - IntegrationChapter 16.7 - MultiplicityChapter 16.8 - Drawing The Expected 1h Nmr Spectrum Of A CompoundChapter 16.9 - Using 1h Nmr Spectroscopy To Distinguish Between CompoundsChapter 16.10 - Analyzing A 1h Nmr SpectrumChapter 16.12 - Chemical Shifts In 13c Nmr SpectroscopyChapter 16.13 - Dept 13c Nmr SpectroscopyChapter 17 - Conjugated Pi Systems And Pericyclic ReactionsChapter 17.1 - Classes Of DienesChapter 17.2 - Conjugated DienesChapter 17.3 - Molecular Orbital TheoryChapter 17.4 - Electrophilic AdditionChapter 17.5 - Thermodynamic Control Vs. Kinetic ControlChapter 17.7 - Diels-alder ReactionsChapter 17.8 - Mo Description Of CycloadditionsChapter 17.9 - Electrocyclic ReactionsChapter 17.10 - Sigmatropic RearrangementsChapter 17.11 - Uv-vis SpectroscopyChapter 17.12 - ColorChapter 18 - Aromatic CompoundsChapter 18.2 - Nomenclature Of Benzene DerivativesChapter 18.4 - Stability Of BenzeneChapter 18.5 - Aromatic Compounds Other Than BenzeneChapter 18.6 - Reactions At The Benzylic PositionChapter 18.7 - Reduction Of The Aromatic MoietyChapter 18.8 - Spectroscopy Of Aromatic CompoundsChapter 19 - Aromatic Substitution ReactionsChapter 19.2 - HalogenationChapter 19.3 - SulfonationChapter 19.4 - NitrationChapter 19.5 - Friedel-crafts AlkylationChapter 19.6 - Friedel-crafts AcylationChapter 19.7 - Activating GroupsChapter 19.8 - Deactivating GroupsChapter 19.9 - Halogens: The ExceptionChapter 19.10 - Determining The Directing Effects Of A SubstituentChapter 19.11 - Multiple SubstituentsChapter 19.12 - Synthesis StrategiesChapter 19.13 - Nucleophilic Aromatic SubstitutionChapter 19.14 - Elimination-additionChapter 19.15 - Identifying The Mechanism Of An Aromatic Substitution ReactionChapter 20 - Aldehydes And KetonesChapter 20.2 - NomenclatureChapter 20.3 - Preparing Aldehydes And Ketones: A ReviewChapter 20.4 - Introduction To Nucleophilic Addition ReactionsChapter 20.5 - Oxygen NucleophilesChapter 20.6 - Nitrogen NucleophilesChapter 20.7 - Hydrolysis Of Acetals, Lmines, And EnaminesChapter 20.8 - Sulfur NucleophilesChapter 20.9 - Hydrogen NucleophilesChapter 20.10 - Carbon NucleophilesChapter 20.11 - Baeyer-villiger Oxidation Of Aldehydes And KetonesChapter 20.12 - Synthesis StrategiesChapter 20.13 - Spectroscopic Analysis Of Aldehydes And KetonesChapter 21 - Carboxylic Acids And Their DerivativesChapter 21.2 - Nomenclature Of Carboxylic AcidsChapter 21.3 - Structure And Properties Of Carboxylic AcidsChapter 21.4 - Preparation Of Carboxylic AcidsChapter 21.5 - Reactions Of Carboxylic AcidsChapter 21.6 - Introduction To Carboxylic Acid DerivativesChapter 21.7 - Reactivity Of Carboxylic Acid DerivativesChapter 21.8 - Preparation And Reactions Of Acid ChloridesChapter 21.9 - Preparation And Reactions Of Acid AnhydridesChapter 21.10 - Preparation Of EstersChapter 21.11 - Reactions Of EstersChapter 21.12 - Preparation And Reactions Of AmidesChapter 21.13 - Preparation And Reactions Of NitrilesChapter 21.14 - Synthesis StrategiesChapter 21.15 - Spectroscopy Of Carboxylic Acids And Their DerivativesChapter 22 - Alpha Carbon Chemistry: Enols And EnolatesChapter 22.1 - Introduction To Alpha Carbon Chemistry: Enols And EnolatesChapter 22.2 - Alpha Halogenation Of Enols And EnolatesChapter 22.3 - Aldol ReactionsChapter 22.4 - Claisen CondensationsChapter 22.5 - Alkylation Of The Alpha PositionChapter 22.6 - Conjugate Addition ReactionsChapter 22.7 - Synthesis StrategiesChapter 23 - AminesChapter 23.2 - Nomenclature Of AminesChapter 23.3 - Properties Of AminesChapter 23.4 - Preparation Of Amines: A ReviewChapter 23.5 - Preparation Of Amines Via Substitution ReactionsChapter 23.6 - Preparation Of Amines Via Reductive AminationChapter 23.7 - Synthesis StrategiesChapter 23.8 - Acylation Of AminesChapter 23.9 - The Hofmann EliminationChapter 23.10 - Reactions Of Amines With Nitrous AcidChapter 23.11 - Reactions Of Aryldiazonium IonsChapter 23.12 - Nitrogen HeterocyclesChapter 23.13 - Spectroscopy Of AminesChapter 24 - CarbohydratesChapter 24.2 - Classifying MonosaccharidesChapter 24.4 - Configuration Of KetosesChapter 24.5 - Cyclic Structures Of MonosaccharidesChapter 24.6 - Reactions Of MonosaccharidesChapter 24.7 - DisaccharideChapter 25 - Amino Acids, Peptides, And ProteinsChapter 25.2 - Structure And Properties Of Amino AcidsChapter 25.3 - Amino Acid SynthesisChapter 25.4 - Structure Of PeptidesChapter 25.5 - Sequencing A PeptideChapter 25.6 - Peptide SynthesisChapter 25.7 - Protein StructureChapter 26 - LipidsChapter 26.2 - WaxesChapter 26.3 - TriglyceridesChapter 26.4 - Reactions OftriglyceridesChapter 26.5 - PhospholipidsChapter 26.6 - SteroidsChapter 26.7 - ProstaglandinsChapter 26.8 - TerpenesChapter 27 - Synthetic PolymersChapter 27.2 - Nomenclature Of Synthetic PolymersChapter 27.3 - CopolymersChapter 27.4 - Polymer Classification By Reaction TypeChapter 27.5 - Polymer Classification By Mode Of AssemblyChapter 27.6 - Polymer Classification By StructureChapter 27.8 - Polymer Recycling
Book Details
Organic chemistry is not merely a compilation of principles, but rather, it is a disciplined method of thought and analysis. Success in organic chemistry requires mastery in two core aspects: fundamental concepts and the skills needed to apply those conce
Sample Solutions for this Textbook
We offer sample solutions for Organic Chemistry, 2nd Edition (wileyplus Access Code) homework problems. See examples below:
Carbon (C), hydrogen (H) valency in C4H10 Carbon is tetravalent whereas hydrogen is monovalent...Explanation: To draw all carbon atoms for given bond-line structures of compounds. Put a carbon atom...Explanation: The most acidic proton of the given acid (a) is O-H proton, because deprotonation at...The longest chain of the given compounds is identified by counting the number of carbon atoms...Explanation: Draw the structure of the given molecule and find the chiral centers. Chiral centers of...Explanation: To find: Bond-dissociation energy of the given compounds. Draw the given molecule and...Explanation: To identify: The systematic name and the common name for the given molecules. Find the...To identify: The systematic name for the given structure (a). Draw the given molecule (a) and find...Explanation: To explain: the conditions for the given reaction. Given reaction is shown below. Clear...
Explanation: The systematic name for the given molecule (a). Draw the given molecule (a) and find...Explanation: The radical resonance structure of the given molecule The radical resonance structure...Explanation: Identify the reagents used in formation of products 1,2 and 3 from given substrate....Explanation: To find: IUPAC name of the compound The IUPAC name of the given organic compound is...Explanation: Predict the IUPAC nomenclature. The IUPAC name must contain all the information...For the given compound A the responsible bonds are, Conjugated carbonyl and conjugated C=C bonds....Explanation: To predict: the structure for the given molecular formula. C5H10 Calculate HDI Value...Explanation To analyze the presence of prefix suffix and root name in the given IUPAC name and draw...Explanation: 4-ethylbenzoic acid From the structure of the compound it is clear that the parent...Explanation: Chlorination of benzene. Benzene reacts with Chlorine in an electrophilic substitution...Explanation (-C=O, -C-C-) in carbon chain or carbon skeleton, the substituents for naming the...Explanation: (a) To find: The increasing acidity order for the given set of compounds. Determine the...Explanation: Deprotonation of the highlighted hydrogen and resonance stabilization From the above...Explanation: The given compound, spermine contains totally four nitrogen atoms. Among them, two of...Explanation: The OH group connected to C3 is pointing to the right side, so it is called as D-sugar....Explanation: Linear formula for L-valine The linear formula for L-valine is (CH3)2CHCH(NH2)CO2H ....Explanation: Structure of tripalmitolein The structure of tripalmitolein is drawn as above. In...Explanation: To draw and name the polymer when vinyl acetate undergoes polymerization Draw the...
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