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Physical Chemistry

2nd Edition

Ball, David W. (david Warren), BAER, Tomas

Publisher: Wadsworth Cengage Learning,

ISBN: 9781133958437

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Chapter

Section

Problem 1.1E:

A bomb calorimeter is a study metal vessel in which samples can be ignited and the amount of heat...

Problem 1.4E:

Use the equalities listed in Table 1.1 to convert the given values to the desired units. a 12.56 L...

Problem 1.6E:

A standard drinking straw is 23 cm tall. What pressure difference is needed to raise a column of...

Problem 1.7E:

Referring to the previous exercise: Without special pressurized equipment, the maximum pressure...

Problem 1.8E:

A pot of cold water is heated on a stove, and when the water boils, a fresh egg is placed in the...

Problem 1.9E:

hat difference is necessary for heat to flow between two systems? Can you think of an exception to...

Problem 1.10E:

What is the value of FT for a sample of gas whose volume is 2.97 L and pressure is 0.0553 atm? What...

Problem 1.11E:

What is the value of FP for a sample of gas whose temperature is -33.0 C and volume is 0.0250 L?...

Problem 1.12E:

Calculate the value of the constant in equation 1.9 for a 1.887 mol gas sample with a pressure of...

Problem 1.13E:

Hydrogen gas is used in weather balloon because it is less expensive than Helium. Assume that 5.57 g...

Problem 1.14E:

A weather balloon having an initial volume of 67 L and 1.04 atm is weighed down and dropped into the...

Problem 1.15E:

A 2.0 L soda bottle is pressurized with 4.5 atm of CO2 at 298 K. If the temperature is increased to...

Problem 1.16E:

The Mount Pinatubo volcano eruption in 1991 released an estimated 1.82 x 1013g of SO2 into the...

Problem 1.17E:

Show that one value of R, with its associated units, equals another value of R with its different...

Problem 1.18E:

Scottish physicist W. J. M. Rankine proposed an absolute temperature scale based on the Fahrenheit...

Problem 1.20E:

Calculations using STP and SATP use the same? Different? values of R. Choose one phrase to make the...

Problem 1.21E:

Pressures of gases in mixtures are referred to as partial pressures and are additive. 1.00 L of He...

Problem 1.22E:

Earths atmosphere is approximately 80 N2 and 20 O2. If the total atmospheric pressure at sea level...

Problem 1.23E:

The atmospheric surface pressure on Venus is 90 bar and is composed of 96 carbon dioxide and...

Problem 1.24E:

The atmospheric surface pressure on Mars is 4.50 torr and is composed entirely of carbon dioxide....

Problem 1.25E:

In the reaction between hydrochloric acid and magnesium 100.0 g of HCl aq is reacted. What volume of...

Problem 1.26E:

In the anaerobic oxidation of glucose by yeast, CO2 is produced: If 1.56 L of CO2 were produced at...

Problem 1.27E:

What are the slopes of the following lines at the point x = 5? At x = 10? a y = 5x 7 b y = 3x2 5x ...

Problem 1.28E:

For the following function, evaluate the derivatives in a-f below. F(w,x,y,z)=3xy2+w3z332yxy2z3w...

Problem 1.31E:

Why do you think that none of the above exercises ask you to take a derivative with respect to R? Is...

Problem 1.32E:

a Rewrite the ideal gas law as volume being a function of pressure and temperature. b What is the...

Problem 1.33E:

When a given amount of air is let out of an automobile tire, it changes it volume and pressure...

Problem 1.34E:

A derivative with respect to the same variable can be taken more than once: and is called the second...

Problem 1.36E:

a What is the value of the compressibility for an ideal gas? b Does the value vary with p, V, T, or...

Problem 1.37E:

Liquid nitrogen comes in large cylinders that required special tank carts and hold 120 L of liquid...

Problem 1.38E:

Calculate the Boyle temperatures for carbon dioxide, oxygen, and nitrogen using the van der Waals...

Problem 1.39E:

Determine the expression for p / VT, n for a van der Waals gas and for the virial equation in terms...

Problem 1.40E:

What are the units of the virial coefficient C? of C?

Problem 1.41E:

Table 1.4 show that the second virial coefficient B for He is negative at low temperature, seems to...

Problem 1.42E:

Use Table 1.5 to list the gases from most ideal to least ideal. What trend or trends are obvious...

Problem 1.44E:

The van der Waals constant b can be used to estimate molecular sizes, assuming the molecules are...

Problem 1.45E:

Under what conditions would the van der Waals constant b be negative? Do you think there are any...

Problem 1.46E:

By definition, the compressibility of an ideal gas is 1. By approximately what percentage does this...

Problem 1.47E:

The second virial coefficient B and the third viral coefficient C for Ar are -0.021 L/mol and 0.0012...

Problem 1.48E:

Use the approximation 1 x-1 1 x x2 to determine an expression for the virial coefficient C in...

Problem 1.49E:

Why is nitrogen a good choice for the study of ideal gas behavior around room temperature?

Problem 1.51E:

Numerically evaluate for one mole of methane acting as a van der Waals gas at a T = 298 K and V =...

Problem 1.52E:

Under what conditions of volume does a van der Waals gas behave like an ideal gas? Use the van der...

Problem 1.53E:

At high temperatures, one of the van der Waals constants can be ignored. Which one? Justify your...

Problem 1.54E:

Under what conditions of temperature does a Redlich-Kwong gas behave like an ideal gas? Use the...

Problem 1.55E:

The Berthelot equation of state for one mole of gas is p=RTV-b-aTV2 Where a and b are constants...

Problem 1.56E:

The Dieterici equation of state for one mole of gas is p=RTe-aVRTV-b Where a and b are constants...

Problem 1.57E:

Referring to exercises 1.6 and 1.7, does it matter if the pressure difference is caused by an ideal...

Problem 1.58E:

Write two other forms of the cyclic rule in equation 1.26, using the mnemonic in Figure 1.11.

Problem 1.59E:

Use Figure 1.11 to construct the cyclic rule equivalent of Does the answer make sense in light of...

Problem 1.60E:

What are the units for and ?

Problem 1.61E:

Calculate for one mole of an ideal gas at STP and SATP.

Problem 1.62E:

Calculate for one mole of an ideal gas at STP and SATP.

Problem 1.63E:

Why is it difficult to determine an analytic expression for and for a van der Waals gas?

Problem 1.64E:

Show that = T/p for an ideal gas.

Problem 1.65E:

Determine an expression for V/T p, n in terms of and . Does the sign on the expression make sense...

Problem 1.66E:

Density is defined as molar mass, M, divided by molar volume: M,V and pd=MV Evaluate d/ T p, n for...

Problem 1.67E:

Write the fraction / in a different form using the cyclic rule of partial derivatives.

Problem 1.68E:

Perform a units analysis on the exponent of the barometric function and verify that the overall...

Problem 1.69E:

Using the barometric formula, calculate the expected air pressure in Colorado Springs, Colorado,...

Problem 1.70E:

The barometric formula can also be used for elevations below sea level. In such cases, h is...

Problem 1.71E:

Calculate the average grade using equation 1.32 if the scores on a 10-point quiz are 3, 5, 7, 3, 4,...

Problem 1.72E:

Calculate the average grade using equation 1.32 if the scores on a 10-point quiz are 5, 5, 5, 5, 10,...

Problem 1.73E:

What is the ratio of the populations of two energy states whose energies differ by 500 J at a 200 K...

Problem 1.74E:

What is the ratio of the populations of two energy states whose energies differ by 1000 J at a 200 K...

Problem 1.75E:

Determine the expected for translational and rotational motions, in RT units, for these gases. a Ne...

Problem 1.76E:

Determine the expected for translation and rotational motions, in RT units, for theses gases. a CN2...

Problem 1.77E:

Explain why it is difficult to determine a simple value for for vibration degrees of freedom. What...

Problem 1.78E:

Table 1.4 gives different values of the second virial coefficient B for different temperatures....

Show more chapters

Chapter 1 - Gases And The Zeroth Law Of ThermodynamicsChapter 2 - The First Law Of ThermodynamicsChapter 3 - The Second And Third Laws Of ThermodynamicsChapter 4 - Gibbs Energy And Chemical PotentialChapter 5 - Introduction To Chemical EquilibriumChapter 6 - Equilibria In Single-component SystemsChapter 7 - Equilibria In Multiple-component SystemsChapter 8 - Electrochemistry And Ionic SolutionsChapter 9 - Pre-quantum MechanicsChapter 10 - Introduction To Quantum Mechanics

Chapter 11 - Quantum Mechanics: Model Systems And The Hydrogen AtomChapter 12 - Atoms And MoleculesChapter 13 - Introduction To Symmetry In Quantum MechanicsChapter 14 - Rotational And Vibrational SpectroscopyChapter 15 - Introduction To Electronic Spectroscopy And StructureChapter 16 - Introduction To Magnetic SpectroscopyChapter 17 - Statistical Thermodynamics: IntroductionChapter 18 - More Statistical ThermodynamicsChapter 19 - The Kinetic Theory Of GasesChapter 20 - KineticsChapter 21 - The Solid State: CrystalsChapter 22 - Surfaces

With its easy-to-read approach and focus on core topics, PHYSICAL CHEMISTRY, 2e provides a concise, yet thorough examination of calculus-based physical chemistry. The Second Edition, designed as a learning tool for students who want to learn physical chemistry in a functional and relevant way, follows a traditional organization and now features an increased focus on thermochemistry, as well as new problems, new two-column examples, and a dynamic new four-color design. Written by a dedicated chemical educator and researcher, the text also includes a review of calculus applications as applied to physical chemistry.

We offer sample solutions for Physical Chemistry homework problems. See examples below:

Show more sample solutions

A bomb calorimeter is a study metal vessel in which samples can be ignited and the amount of heat...Calculatethe work performed by a person whoexertsa force of 30 NN = newtonstomove abox 30metersif...Decide whether the following processes will be spontaneous, and why. The why can be general, not...List the sets of conditions that allow dS, dU, and dH of a process in a system act as a spontaneity...5.1. Can a battery that has a voltage be considered a system at equilibrium? How about a dead...6.1. Determine the number of components in the following systems: (a) an iceberg of pure ; (b)...7.1. Consult Example and assume that now your mixed drink has an olive in it. Now how many degrees...8.1. What is the charge on a small sphere that is attracted to another sphere having charge if the...For an object having mass m falling in the z direction, the kinetic energy is 12mz and the potential...

State the postulates of quantum mechanics introduced throughout the chapter in your own words.Convert 3.558mdyn/A into units of N/m.In the Stern-Gerlach experiment, silver atoms were used. This was a good choice, as it turned out....In your own words, explain why an object that has more symmetry elements is said to have higher...Why wont a rotational spectrum be observed for the rotation of a linear molecule about its linear...Linearly polarized light can be assigned a specific irreducible representation of a symmetry point...What is the difference between a magnetic field vector and a magnetic dipole vector?Draw the possible ways of putting two balls into three boxes, one ball per box. Are your drawings...Using a table of nuclear spin states, determine qnuc for a12C atoms, b56Fe atoms, c1H atoms,...Define postulate in the scientific sense. You may have to consult a good dictionary that can define...Write three additional rate relationships like equation 20.5 using the definition of the rate from...Give an atomic-level reason why ionic crystals are brittle.Using the explanation of unbalanced forces as the source of surface tension, justify why it requires...

Corresponding editions of this textbook are also available below:

PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.

2 Edition

ISBN: 9781285074788

Physical Chemistry

2 Edition

ISBN: 9781285969770

Bundle: Physical Chemistry, 2nd + Student Solutions Manual

2 Edition

ISBN: 9781285257594

Physical Chemistry

1 Edition

ISBN: 9780534266585

Fisicoquimica/ Physical Chemistry (spanish Edition)

1 Edition

ISBN: 9789706863287

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