13. p-nitroaniline reacts with NaNO₂/HCI at 0°C 14. product of no. 13 reacts with CuCN/KCN

Chemistry for Today: General, Organic, and Biochemistry
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ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Chapter15: Carboxylic Acids And Esters
Section: Chapter Questions
Problem 15.69E
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Please answer item number 14 only.

1. Draw the structure of the organic product/s when:
1. propanal reacts with ammoniacal AgNO, (Tollens' reagent)
2. 3-methylbutanal forms a cyanohydrin
3. 4-methyl-2-pentanone reacts with Grignard reagent, CH3CH₂MgBr
4. 2-methylhexanal reacts with 2 moles of ethanol in dry acid
5. two moles of phenylacetaldehyde undergo condensation to give an aldol
6. the product of no.5 undergoes dehydration
7.
D-arabinose reacts with dilute nitric acid with heating
8. benzoic acid reacts with excess isopropyl alcohol and acid catalyst
9. propanoic anhydride reacts with ammonia
10. ethyl benzoate undergoes acid catalyzed hydrolysis
11. two moles of ethyl phenylacetate undergo condensation to give a beta-keto ester.
12. a trimyristin undergoes hydrogenolysis
13. p-nitroaniline reacts with NaNO₂/HCI at 0°C
14. product of no. 13 reacts with CuCN/KCN
HO
-H
-OH
-OH
CH₂OH
D-arabinose
H-
H
-CH₂-C-H
phenylacetaldehyde
11
H₂C-O-C
O
11
HC-0-C.
L i
H₂C-O-C.
-CH₂-C-OCH₂CH3
ethyl phenylacetate
trimyristin
Transcribed Image Text:1. Draw the structure of the organic product/s when: 1. propanal reacts with ammoniacal AgNO, (Tollens' reagent) 2. 3-methylbutanal forms a cyanohydrin 3. 4-methyl-2-pentanone reacts with Grignard reagent, CH3CH₂MgBr 4. 2-methylhexanal reacts with 2 moles of ethanol in dry acid 5. two moles of phenylacetaldehyde undergo condensation to give an aldol 6. the product of no.5 undergoes dehydration 7. D-arabinose reacts with dilute nitric acid with heating 8. benzoic acid reacts with excess isopropyl alcohol and acid catalyst 9. propanoic anhydride reacts with ammonia 10. ethyl benzoate undergoes acid catalyzed hydrolysis 11. two moles of ethyl phenylacetate undergo condensation to give a beta-keto ester. 12. a trimyristin undergoes hydrogenolysis 13. p-nitroaniline reacts with NaNO₂/HCI at 0°C 14. product of no. 13 reacts with CuCN/KCN HO -H -OH -OH CH₂OH D-arabinose H- H -CH₂-C-H phenylacetaldehyde 11 H₂C-O-C O 11 HC-0-C. L i H₂C-O-C. -CH₂-C-OCH₂CH3 ethyl phenylacetate trimyristin
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