1A 2A 3B 4B 5B (1) (2) (3) (4) 68 7B 8B (5) (6) 1B 23 3A (9) (10)' (11) (12) (13) (14) (15) (16) (17) 4.0 (7) 44 5A 6A TA 3.0 2.0 1.0 4.02 2. 3,5 3.0 0.0 Li 1.0 Be 1.5 B 2.0 2.5 CI 3.0 2.5 Si 1.8 2.1 Mg 1.2 Al 1.5 Br 2,8 Na 0.9 Fe Cu 1.9 Zn Ga As 20 Se 2.4 Cr Co NI Ti 1.5 Mn 1.5 Ge 1.8 181,8 18 Sc 1.3 1.6 1.6 1.6 Ag 3 1.6 K 0.8 Ca 1.0 Ru 2.2 Rh Pd Sn Sb 1.9 1.8 Te 2.1 2.5 Nb 1.6 Mo 1.8 2.2 2.2 1. CdIn 1.9 Zr 1.4 . 17 Y Sr 1.0 Au 2.4 At 2.2 Rb 1.2 Os Ir Pt Po Re 1.9 BI TI 1.8 Pb w 1.7 2.22.2 0.8 Ta 2.2 1.9 1.9 2.0 La 1.1 Hf 1.3 1.5 Ba 0.9 Cs 0.7 Ac Ra 0.9 Fr 1,1 0.7 Lu Gd Tb Dy Ho 121.2 1.11.2 1.21.2 1.21,2 1.2 121.3 Cf Er Tm Yb Pr Nd Pm Sm Eu Ce 1.1 1.1 1.1 No Es Fm Md Th 1.3 Pa 1.5 Np Pu Am Cm Bk 1.7 1.3 1.31.3 1.31.3 1.31.31.31.31.5 |0.7 - 1.4 Figure 9.19 The Pauling electronegativ- ity (EN) scale. The height of each post is proportional to the EN, which is shown on top. The key has several EN cutoffs. In 1.5 - 1.9 2.0 - 2.9 3.0 - 4.0 the main groups, EN increases across and decreases down. The transition and inner transition elements show little change in EN. Here hydrogen is placed near ele- ments with similar EN values. Period Electronegativity Electronegativity 2. Period

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In developing the concept of electronegativity, Pauling used the term excess bond energy for the difference between the actual bond energy of X¬Y and the average bond energies of X¬X and Y¬Y (see text discussion for the case of HF). Based on the values as shown, which of the following substances contains bonds with no excess bond energy?
(a) PH3 (b) CS2 (c) BrCl (d) BH3 (e) Se8

1A
2A
3B
4B
5B
(1)
(2)
(3)
(4)
68
7B
8B
(5) (6)
1B
23 3A
(9) (10)' (11) (12) (13) (14) (15) (16) (17)
4.0
(7)
44
5A
6A TA
3.0
2.0
1.0
4.02
2.
3,5
3.0
0.0
Li
1.0
Be
1.5
B
2.0
2.5
CI
3.0
2.5
Si
1.8
2.1
Mg
1.2
Al
1.5
Br
2,8
Na
0.9
Fe
Cu
1.9 Zn Ga
As
20
Se
2.4
Cr
Co
NI
Ti
1.5
Mn
1.5
Ge
1.8
181,8 18
Sc
1.3
1.6
1.6 1.6
Ag
3
1.6
K
0.8
Ca
1.0
Ru
2.2
Rh Pd
Sn Sb
1.9
1.8
Te
2.1
2.5
Nb
1.6
Mo
1.8
2.2 2.2 1. CdIn
1.9
Zr
1.4
. 17
Y
Sr
1.0
Au
2.4
At
2.2
Rb
1.2
Os
Ir
Pt
Po
Re
1.9
BI
TI
1.8
Pb
w
1.7
2.22.2
0.8
Ta
2.2
1.9 1.9 2.0
La
1.1
Hf
1.3
1.5
Ba
0.9
Cs
0.7
Ac
Ra
0.9
Fr
1,1
0.7
Lu
Gd Tb Dy Ho
121.2 1.11.2 1.21.2 1.21,2 1.2 121.3
Cf
Er Tm Yb
Pr
Nd
Pm Sm Eu
Ce
1.1
1.1 1.1
No
Es Fm Md
Th
1.3
Pa
1.5
Np Pu Am Cm Bk
1.7
1.3
1.31.3 1.31.3 1.31.31.31.31.5
|0.7 - 1.4
Figure 9.19 The Pauling electronegativ-
ity (EN) scale. The height of each post is
proportional to the EN, which is shown
on top. The key has several EN cutoffs. In
1.5 - 1.9
2.0 - 2.9
3.0 - 4.0
the main groups, EN increases across and
decreases down. The transition and inner
transition elements show little change
in EN. Here hydrogen is placed near ele-
ments with similar EN values.
Period
Electronegativity
Electronegativity
2.
Period
Transcribed Image Text:1A 2A 3B 4B 5B (1) (2) (3) (4) 68 7B 8B (5) (6) 1B 23 3A (9) (10)' (11) (12) (13) (14) (15) (16) (17) 4.0 (7) 44 5A 6A TA 3.0 2.0 1.0 4.02 2. 3,5 3.0 0.0 Li 1.0 Be 1.5 B 2.0 2.5 CI 3.0 2.5 Si 1.8 2.1 Mg 1.2 Al 1.5 Br 2,8 Na 0.9 Fe Cu 1.9 Zn Ga As 20 Se 2.4 Cr Co NI Ti 1.5 Mn 1.5 Ge 1.8 181,8 18 Sc 1.3 1.6 1.6 1.6 Ag 3 1.6 K 0.8 Ca 1.0 Ru 2.2 Rh Pd Sn Sb 1.9 1.8 Te 2.1 2.5 Nb 1.6 Mo 1.8 2.2 2.2 1. CdIn 1.9 Zr 1.4 . 17 Y Sr 1.0 Au 2.4 At 2.2 Rb 1.2 Os Ir Pt Po Re 1.9 BI TI 1.8 Pb w 1.7 2.22.2 0.8 Ta 2.2 1.9 1.9 2.0 La 1.1 Hf 1.3 1.5 Ba 0.9 Cs 0.7 Ac Ra 0.9 Fr 1,1 0.7 Lu Gd Tb Dy Ho 121.2 1.11.2 1.21.2 1.21,2 1.2 121.3 Cf Er Tm Yb Pr Nd Pm Sm Eu Ce 1.1 1.1 1.1 No Es Fm Md Th 1.3 Pa 1.5 Np Pu Am Cm Bk 1.7 1.3 1.31.3 1.31.3 1.31.31.31.31.5 |0.7 - 1.4 Figure 9.19 The Pauling electronegativ- ity (EN) scale. The height of each post is proportional to the EN, which is shown on top. The key has several EN cutoffs. In 1.5 - 1.9 2.0 - 2.9 3.0 - 4.0 the main groups, EN increases across and decreases down. The transition and inner transition elements show little change in EN. Here hydrogen is placed near ele- ments with similar EN values. Period Electronegativity Electronegativity 2. Period
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