
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Question

Transcribed Image Text:5. The following questions involve titrations of dimethylamine, (CH3)2NH, a weak base, Kb = 2.2
x 104, with nitric acid, HNO3, a strong acid.
A) Given the concentration of the acid and base are both 0.1M and 500 mL of dimethylamine is
in the flask and nitric acid is in the burette, sketch the titration curve to a final volume of 1000
mL. Identify and label:
• the initial pH (+/-1)
the final pH (+/- 1)
• the equivalence point at an appropriate pH (+/- 1) and volume (+/- 100 mL)
the buffer region at the appropriate pH (+/- 1) and volume (+/- 100 mL)
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution
Trending nowThis is a popular solution!
Step by stepSolved in 3 steps

Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 0.3456 g of a solid acid is dissolved in 50 mL of water in a flask and a few drops of phenolphthalein are added to the solution. A buret containing 0.2545 M NaOH is prepared with an initial volume of 10.50 mL. The acid is accidentally titrated with the base beyond the end point, so 1.52 mL of 0.187 M HCl are added to the flask. The titration with the base is continued to a final volume reading of 40.55 mL. Calculate the molar mass of the solid acid.arrow_forwardAn unknown potassium hydroxide solution is titrated with a standardized solution of hydrochloric acid. It takes 37.4 mL of the base to reach the endpoint when reacting with 25.0 mL of 0.138 M HCl. What is the molarity of the KOH solution?arrow_forwardWalter White requires a sulfuric acid (Strong acid) solution to use in a very important synthetic reaction. He finds a bottle labeled H2SO4, but by some strange turn of events, he cannot remember the concentration. He decides to perform a titration to determine the concentration of the H2SO4. He pours 22.20 mL of his unknown sulfuric acid solution into a flask and finds that it requires 29.50 mL of 0.57 M KOH (strong base) to reach the endpoint. What is the concentration of Walter White's sulfuric acid solution? (Enter your numeric answer only, do not use scientific notation, enter 2 decimal places with your answer) For reference: KOH = 56.106g/mol H2SO4= 98.079g/mol Avagadro's number 6.022x1023arrow_forward
- A 50.0 mL solution of Mg(OH)2 of unknown concentration is titrated with 0.348 M HCI. The equivalence point (end point) is reached after 62.8 mL of HCI were dispensed into the Mg(OH)2 solution. What is the molarity concentration of the base?arrow_forwardAn aqueous solution of Ca(OH)2with a concentration of 0.188 M was used to titrate 25.00 mL of aqueous HCl. 18.63 mL of the Ca(OH)2was required to reach the endpoint of the titration. How many moles of base were required to react completely with the acid in this reaction? How many moles of HCl were present in the original 25.00 mL of acid?arrow_forwardFill in the missing words With the given plot, if a 0.1000 M NaOH solution was used to fully precipitate all the Zn2+ in the form of Zn(OH)2 with the addition of 6.00 mL of NaOH, the number of moles of Zn2+ in this 10 mL brass stock solution is mmol. Therefore, there are mmol of Zn2+ in the entire 100-mL brass stock solution, which is g/mol). mg of Zn2+ (FW = 65arrow_forward
- After 10.0 mL of a 0.020 M Ba(OH)2 (aq) are mixed with 15.0 mL of a 0.020 M KOH(aq), what is the molarity of [OH-]?arrow_forwardThe flask contains 10.0 mL HCl and a few drops of phenolphthalein indicator. The buret contains 0.140 M NaOH. It requires 11.0 mL of the NaOH solution to reach the end point of the titration. What is the initial concentration of HCl?arrow_forward6. Acid/base titration is a common method to determine the molarities of acids or bases, the molarity of certain salts can also be determined by titration. It took 22.34 mL of 0.5861 M HCl solution to neutralize 25.00 mL NaNO₂ solution. The acid- dissociation constant of HNO₂ is 4.511 × 10-¹. NaNO₂ + HCl → HNO₂ + NaCl Please answer the following questions. A What is pH of the NaNO₂ solution before titration? Hint, calculate the molarity of the NaNO₂ solution first. pH = Please provider your answer below. ( Check answer 7²² B. M HCl solution was added to the NaNO2 solution? pH = 00 0 Please provider your answer below. What is the pH when 12.78 mL of 0.5861 (0) Check answer C. What is the pH when 14.39 mL of 0.5861 M HCl solution was added to the NaNO₂ solution AFTER the equivalence point? pH = Please provider your answer below. 00 0 °C? pH= Please provider your answer below. Check answer What is the pH at equivalence point at 25 A → ← Check answer ← $ H $arrow_forward
- what is the molarity of a solution of phosphoric acid (a tricrotic acid) if 10.00 mL of the phosphoric acid solution requires 38.11 mL of 0.2412 M NaOH solution to titrate it?arrow_forwardSuppose 0.473 grams of a solid monoprotic acid are titrated with 16.32 mL of 0.106 M NaOH. What is the molar molar mass of the solid acid?arrow_forwardThe principal ingredient of certain commercial antacids is calcium carbonate, CaCO3. A student titrates 25.0 mL of antacid with hydrochloric acid; the reaction is CaCO3 + 2HCl rightwards arrow CaCl2 + CO2 + H2O If 38.5 mL of 0.200 M HCl is required for complete reaction, what is the molarity of antacid? 0.254 M 0.154 M 0.015 M 0.025 Marrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY

Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning

Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning

Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning

Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY