7. Predict the products. Finish the following reactions: Show the organic products, reactants, or reaction conditions with stereochemistry as appropriate. ALL reactions proceed to give one or more products. a) b) OTS Br OMS KOtBu HOtBu H₂O Heat NaCN
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- Draw a structural formula for the major organic product of the reaction shown below. & CH₂ (oran CH3CH₂O -CuLi 2 ether You do not have to consider stereochemistry. Sn [F ? ChemDoodle H3O +Provide the structure(s) of the expected major organic product of the reaction shown. 1) Disiamylborane 2) H₂O₂, NaOH OI O II ||| O IV OV CH3CH₂C(CH3)2C=CH OH OH xx xo IV4. What are the products obtained from the following elimination reaction? Indicate the major product. CH;CH2CCH3 H2O CI 5. a) Determine the major product that is formed when the alkyl halide reacts with a hydroxide ion in an elimination reaction. CH;CH,CH,CH,CCH3 Br b) For the major elimination product obtained in 5a), which stereoisomer (cis or trans) is obtained in greater yield? Draw the two isomers and provide the names of the compounds.
- CH3 CH3 CH3 CH;=ĊCH,CHCH;OH H2SO4, H3C H3C Referring to the above reaction: 1. Which atom does the H2SO4 first remove? 2. Identify the reaction if it's hydrogenation, hydrohalogenation, etc. 3. Propose a mechanism for the reaction, using the arrow formalism to indicate the flow of electrons.Melamine, used as a fire retardant and a component of the writing surface of white boards, can be prepared from s-trichlorotriazine through a series of SNAr reactions with ammonia. The first substitution takes place rapidly at room temperature. The second substitution takes place near 100 °C, and the third substitution requires even higher temperature and pressure. Provide an explanation fatr this reactivity.The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?
- What is the expected major product of this reaction? OH H₂N I H₂N H₂N 85% H3PO4, A H₂N ||| ? H₂N IVDraw the alkene that would react with the reagent given to account for the product formed. ? + H₂O ● You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. 8 H₂SO4 // CH3 CH3CHCCH3 OH CH3 ? [F Previous Email Instruct1. Predict the structures of all products indicated by each reaction. State the mechanism and briefly explain your answer. a 'OH "Br HCI (conc, aq) 4 products! NaSCH 3 CH3CN one product
- 9. Draw the constitutional isomer formed when the following alkenes are treated with each set of reagents: [1] H20, H2SO4; or [2] BH3 followed by H2O2, "OH. A io onutouTC.rvinmmoo ewo ebyoleen.g er besibhoyn motis M doso al waH s b. a. Seblaar molsHsno isq onol nose 2eob isticho to eqyt ewni.d Cnistnoo ennug 29ob anodogle yoam woH.o O bns 18 to alnemala erlT nertw bemot witam-S ae doue anexie leohtemmyeni1. Identify the products of the following transformations. Br HCI CH; H;C-c=CH, 1. BH3 2. HO, H;0,, H,0 H*, H;O Br2 H,ODraw the organic product of the following reaction. CH3 m-CICgH,CO;H • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If the reaction produces a racemic mixture, just draw one stereoisomer. • If more than one product is possible, only draw the major product. opy aste