Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
7
![a. Propose a plausible mechanism for the following Heck reaction
TBSO
Pd(PPH3)4
K2CO3
H.
OTBS
2.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F0224b761-78f5-473f-946e-d3a8a01cef39%2F22df9e68-aaac-4f39-aa06-99658abbb454%2Fa41m8o_processed.png&w=3840&q=75)
Transcribed Image Text:a. Propose a plausible mechanism for the following Heck reaction
TBSO
Pd(PPH3)4
K2CO3
H.
OTBS
2.
![b. The product of the reaction above is not the only one that could possibly form. In
fact, if you change up the migratory insertion step, you could make three more
isomeric structures. What do they look like? What is your guess for why they
aren't actually observed? (Assume the reaction yields only one diastereomer
regardless of which mechanistic path is followed.)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F0224b761-78f5-473f-946e-d3a8a01cef39%2F22df9e68-aaac-4f39-aa06-99658abbb454%2Fc5oinvq_processed.png&w=3840&q=75)
Transcribed Image Text:b. The product of the reaction above is not the only one that could possibly form. In
fact, if you change up the migratory insertion step, you could make three more
isomeric structures. What do they look like? What is your guess for why they
aren't actually observed? (Assume the reaction yields only one diastereomer
regardless of which mechanistic path is followed.)
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