Fundamentals Of Analytical Chemistry
Fundamentals Of Analytical Chemistry
9th Edition
ISBN: 9781285640686
Author: Skoog
Publisher: Cengage
Bartleby Related Questions Icon

Related questions

Question
100%

Please help me with #2b & #3 using the data.

B. Temperature effects on reaction rates
1. Results
1average
2
3"
4
time (sec)
41.8
24.2
11.7
89.4
1/time (sec-¹)
0.046
0.0413
0.0855
0.0112
In(time)
3.379
3.186
2.459
4.493
Temp (°C)
29.5
35
40.8
12.8
Temp (K)
302.68
308.15
313.95
285.95
1/Temp (1/K)
0.003309
0.003245
0.003185
0.003497
2. Answer these questions:
a. Show mathematically that a plot of In(time) versus 1/Temp should give a straight line
with a slope of E/R.
b. Graph In(time) vs. 1/Temp and determine the slope. From the slope calculate the
activation energy of the reaction.
1/Temp
0.00355
0.0035
0.00345
0.0034
0.00335
0.0033
0.00325
0.0032
0.00315
Chart Title
y = 0.0002x + 0.0028
R² = 0.9686
0.0031
0
1
N
In (Time)
E
4
5
3. Answer these questions:
a. From the graph, determine the reaction time at 20 °C and 30 °C.
b. For this particular reaction, how good is the rule of thumb that "a 10 °C increase
should double the reaction rate"? Explain your answer.
expand button
Transcribed Image Text:B. Temperature effects on reaction rates 1. Results 1average 2 3" 4 time (sec) 41.8 24.2 11.7 89.4 1/time (sec-¹) 0.046 0.0413 0.0855 0.0112 In(time) 3.379 3.186 2.459 4.493 Temp (°C) 29.5 35 40.8 12.8 Temp (K) 302.68 308.15 313.95 285.95 1/Temp (1/K) 0.003309 0.003245 0.003185 0.003497 2. Answer these questions: a. Show mathematically that a plot of In(time) versus 1/Temp should give a straight line with a slope of E/R. b. Graph In(time) vs. 1/Temp and determine the slope. From the slope calculate the activation energy of the reaction. 1/Temp 0.00355 0.0035 0.00345 0.0034 0.00335 0.0033 0.00325 0.0032 0.00315 Chart Title y = 0.0002x + 0.0028 R² = 0.9686 0.0031 0 1 N In (Time) E 4 5 3. Answer these questions: a. From the graph, determine the reaction time at 20 °C and 30 °C. b. For this particular reaction, how good is the rule of thumb that "a 10 °C increase should double the reaction rate"? Explain your answer.
Expert Solution
Check Mark
Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Fundamentals Of Analytical Chemistry
Chemistry
ISBN:9781285640686
Author:Skoog
Publisher:Cengage
Text book image
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Text book image
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
Text book image
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Text book image
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Text book image
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning