Consider the following reaction at 25 °C: 3 NiO(s) + 2 NH₃(g) → 3 Ni(s) + N₂(g) + 3 H₂O(g) Given the information in the table   a. calculate ∆H° for the reaction. b. calculate ∆S° for the reaction. c. Determine the standard free energy for the reaction at 25 °

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Consider the following reaction at 25 °C: 3 NiO(s) + 2 NH₃(g) → 3 Ni(s) + N₂(g) + 3 H₂O(g) Given the information in the table
 
a. calculate ∆H° for the reaction.
b. calculate ∆S° for the reaction.
c. Determine the standard free energy for the reaction at 25 °C.
d. Determine the value of the equilibrium constant at 25 °C.
e. Estimate the temperature at which this reaction would be at equilibrium assuming that enthalpy and entropy are independent of temperature.
f. Determine the value of ∆G assuming that a mixture contains 57.6 g of NiO, 182.3 g of Ni, 0.24 atm of NH₃, 8.54 atm of N₂ and 10.07 atm of H₂O.
Compound
NIO (s)
Ni (s)
NH3 (9)
N₂ (g)
H₂O (g)
AHf° (kJ/mol)
-239.7
0
-46
0
-241.8
Sf° (J/mol-K)
38
29.9
192.5
191.5
188.7
Transcribed Image Text:Compound NIO (s) Ni (s) NH3 (9) N₂ (g) H₂O (g) AHf° (kJ/mol) -239.7 0 -46 0 -241.8 Sf° (J/mol-K) 38 29.9 192.5 191.5 188.7
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