Determine the solubility of lead(II) phosphate in a solution that is 0.0500 M in NaNO,. Ignore ion pairing and acid/base affects but take into account activities. 2.
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![Determine the solubility of lead(II) phosphate in a solution that is 0.0500 M in NaNO,.
Ignore ion pairing and acid/base affects but take into account activities.
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- 4. Calculate the % relative error in solubility by using concentrations instead of activities for Fe(OH)2 in 0.0500 M KNO; (give the source for thermodynamic solubility).Compare the solubility of iron(II) carbonate in each of the following aqueous solutions: Clear All 0.10 M Fe(NO3)2 More soluble than in pure water. 0.10 M (NH,),C03 Similar solubility as in pure water. 0.10 M KCH3CO0 Less soluble than in pure water. 0.10 Μ NaΝO;The volume of water needed to dissolve 0.0624 grams of calcium chromate is L. Assume no volume change upon addition of the solid. The mass of nickel(II) hydroxide that is dissolved in 250 mL of a saturated solution is grams.
- What wt of magnetite should be taken for analysis in order that after converting to a precipitate of Fe2O3.xH2O, the percentage of Fe3O4 in the sample can be found by multiplying the wt in grams of the ignited precipitate (Fe2O3) by 100.The mean activity coefficient of a 0.001.7 :m Mg3(PO,), solution is4. Calculate the percent relative error in the solubility of Fe(OH)3 in 0.0250 M NH&NO3 by using molar concentrations instead of activities.
- The equilibrium for the vorious proportions of the dissociation of the liquid solutions of amyl ester of dichloroacetic ccid (CHCI,.COOC,H,} into the acid (CHCLCOOH) and amylene (C,H was investigated. The inltial amount tor the CHCI,COOC.H used Is 1 mole. Completethe table below Let b the inltial moles of omylene, V the totdl volume cof mixtures in iters, x. be the number of moles of V. 1.05 0.215 0.455 3.12 .af equibrium ond Kc ester outionum constont n.moles per iter. 2.61 0.401 4.45 0.628 3.54 0.794 0.658 3.4423. The Ksp of CuCO3ls) (copper carbonate, a salt) is reported as 2.21x10-11. Determine the solubility (in mg/L) of 1this salt in pure water Constants: The molecular mass (M) of copper carbonate (CuCOg) is 123.554 g mol-1Based on Hume–Rothery’s conditions, which of the following systems would be expected to display unlimited solid solubility? Explain. Mo-Ta; Nb-W; Mg-Zn; and Mg-Cd
- What sorts of additional interactions are taken into account when doing solubility calculations with activities, as opposed to those calculated only using molarities?Calculate the solubility of lead iodate (Pb(IO3)2, Ksp = 3.68 x 10-13).... (a) ... in pure water (b)... in a 0.100 M (Pb(NO3)2 (aq) solutionThere are several steps that are important in ensuring that the maximum amount of precipitate is obtained, that interferences are eliminated, and accurate measurements/results are obtained. Suggest two (2) of these steps and discuss how they could be done.