E. Linkage isomerism is possible for the complex anion. Write the chemical formula of the three possible linkage isomers. F. The complex anion has two geometric isomers, cis and trans. One of these two exhibits optical isomerism. Draw the structures of the enantiomeric pair. G. Malonate (C3H₂04) is a ligand that is similar to oxalate (C₂04). Both are dicarboxylate anions that are capable of bidentate mode of binding through two oxygen atoms. If the oxalate ligands in Na4[Fe(ONO)2(ox)2] are replaced with malonate ligands, what is the systematic name of the resulting coordination compound?
E. Linkage isomerism is possible for the complex anion. Write the chemical formula of the three possible linkage isomers. F. The complex anion has two geometric isomers, cis and trans. One of these two exhibits optical isomerism. Draw the structures of the enantiomeric pair. G. Malonate (C3H₂04) is a ligand that is similar to oxalate (C₂04). Both are dicarboxylate anions that are capable of bidentate mode of binding through two oxygen atoms. If the oxalate ligands in Na4[Fe(ONO)2(ox)2] are replaced with malonate ligands, what is the systematic name of the resulting coordination compound?
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Answer last 3 parts E to G
![1. Consider the coordination compound Na4[Fe(ONO)2(Ox)2].
A. Write the systematic name of the compound.
B. Indicate the (i) oxidation state, (ii) coordination number, and (iii) type of hybridization of the central
metal in the complex anion.
C. Considering the geometry of the complex anion and the ligand field strength, show how the five d
orbitals split and how the d electrons are distributed in these orbitals. Label each d orbital (e.g. dxy).
D. Is the complex anion paramagnetic? Justify your answer.
E. Linkage isomerism is possible for the complex anion. Write the chemical formula of the three possible
linkage isomers.
F. The complex anion has two geometric isomers, cis and trans. One of these two exhibits optical
isomerism. Draw the structures of the enantiomeric pair.
G. Malonate (C3H₂04) is a ligand that is similar to oxalate (C₂04). Both are dicarboxylate anions that
are capable of bidentate mode of binding through two oxygen atoms. If the oxalate ligands in
Na4[Fe(ONO)2(ox)₂] are replaced with malonate ligands, what is the systematic name of the resulting
coordination compound?](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F90c204fe-cc6e-401e-bffc-7dbc94c9c433%2Fd27ba57c-5b21-4bbf-8d84-3582cff16349%2F231ju_processed.png&w=3840&q=75)
Transcribed Image Text:1. Consider the coordination compound Na4[Fe(ONO)2(Ox)2].
A. Write the systematic name of the compound.
B. Indicate the (i) oxidation state, (ii) coordination number, and (iii) type of hybridization of the central
metal in the complex anion.
C. Considering the geometry of the complex anion and the ligand field strength, show how the five d
orbitals split and how the d electrons are distributed in these orbitals. Label each d orbital (e.g. dxy).
D. Is the complex anion paramagnetic? Justify your answer.
E. Linkage isomerism is possible for the complex anion. Write the chemical formula of the three possible
linkage isomers.
F. The complex anion has two geometric isomers, cis and trans. One of these two exhibits optical
isomerism. Draw the structures of the enantiomeric pair.
G. Malonate (C3H₂04) is a ligand that is similar to oxalate (C₂04). Both are dicarboxylate anions that
are capable of bidentate mode of binding through two oxygen atoms. If the oxalate ligands in
Na4[Fe(ONO)2(ox)₂] are replaced with malonate ligands, what is the systematic name of the resulting
coordination compound?
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