Nitroglycerin is a dangerous powerful explosive that violently decomposes when it is shaken or dropped. The Swedish chemist Alfred Nobel (1833-1896) founded the Nobel Prizes with a fortune he made by inventing dynamite, a mixture of nitroglycerin and inert ingredients that was safe to handle. 1. Write a balanced chemical equation, including physical state symbols, for the decomposition of liquid nitroglycerin (C,H,(NO,),) into gaseous dinitrogen, 3) gaseous dioxygen, gaseous water and gaseous carbon dioxide. alb Ar 2. Suppose 87.0 L of carbon dioxide gas are produced by this reaction, at a temperature of -13.0 °C and pressure of exactly 1 atm. Calculate the mass of nitroglycerin that must have reacted. Round your answer to 3 significant digits. Check Explanation Privacy Terms of Use O 2019 McGraw-Hill Education. All Rights Reserved 2:09 PM 12/5/2019 Type here to search hp pg d pg up end ins prt sc home delete f12 f10 f8 f6 15 f3 esc num backspace lock & 6. home CHEE 00 %24 23

Nitroglycerin is a dangerous powerful explosive that violently decomposes when it is shaken or dropped. The Swedish chemist Alfred Nobel (1833-1896) founded the Nobel Prizes with a fortune he made by inventing dynamite, a mixture of nitroglycerin and inert ingredients that was safe to handle. 1. Write a balanced chemical equation, including physical state symbols, for the decomposition of liquid nitroglycerin (C,H,(NO,),) into gaseous dinitrogen, 3) gaseous dioxygen, gaseous water and gaseous carbon dioxide. alb Ar 2. Suppose 87.0 L of carbon dioxide gas are produced by this reaction, at a temperature of -13.0 °C and pressure of exactly 1 atm. Calculate the mass of nitroglycerin that must have reacted. Round your answer to 3 significant digits. Check Explanation Privacy Terms of Use O 2019 McGraw-Hill Education. All Rights Reserved 2:09 PM 12/5/2019 Type here to search hp pg d pg up end ins prt sc home delete f12 f10 f8 f6 15 f3 esc num backspace lock & 6. home CHEE 00 %24 23

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter4: Energy And Chemical Reactions

Section: Chapter Questions

Problem 4.DCP

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On Easter Sunday, April 3, 1983, nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: 2HNO3(aq)+Na2CO3(aq)2NaNO3(aq)+H2O(l)+CO2(g) a. Calculate H for this reaction. Approximately 2.0 104 gal nitric acid was spilled. Assume that the acid was an aqueous solution containing 70.0% HNO3 by mass with a density of 1.42 glcm3. What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? (Hf for NaNO3(aq) = 467 kJ/mol) b. According to The Denver Post for April 4, 1983, authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of H, what was their major concern?
4-77 To convert 1 mol of iron(III) oxide to its elements requires 196.5 kcal: How many grams of iron can be produced if 156.0 kcal of heat is absorbed by a large-enough sample of iron(III) oxide?
Many over-the-counter antacid tablets are now formulated using calcium carbonate as the active ingredient, which enables such tablets to also be used as dietary calcium supplements. As an antacid for gastric hyperacidity, calcium carbonate reacts by combining with hydrochloric acid found in the stomach, producing a solution of calcium chloride, converting the stomach acid to water, and releasing carbon dioxide gas (which the person suffering from stomach problems may feel as a “burp”). Write the unbalanced chemical equation for this process.
A student weighs out a 4.80-g sample of aluminum bromide, transfers it to a 100-mL volumetric flask, adds enough water to dissolve it, and then adds water to the 100-mL mark. What is the molarity of aluminum bromide in the resulting solution?
4.3 Explain the difference between complete and incomplete combustion.
What mass of HCl is contained in 45.0 mL of an aqueous HCl solution that has a density of 1.19 g cm-3 and contains 37.21% HCl by mass?
Suppose that you are closing a cabin in the north woods for the winter and you do not want the water in the toilet tank to freeze. You know that the temperature might get as low as 30. C, and you want to protect about 4.0 L water in the toilet tank from freezing. Calculate the volume of ethylene glycol (density = 1.113 g/mL; molar mass = 62.1 g/mol) you should add to the 4.0 L water.
The notation “(l)” after a substance’s formula indicates it exists in the __________ state.
A rebreathing gas mask contains potassium superoxide, KO2, which reacts with moisture in the breath to give oxygen. 4KO2(s)+2H2O(l)4KOH(s)+3O2(g) Estimate the grams of potassium superoxide required to supply a persons oxygen needs for one hour. Assume a person requires 1.00 102 kcal of energy for this time period. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 1.00 102 kcal of heat, calculate the amount of oxygen consumed and hence the amount of KO2 required. The ff0 for glucose(s) is 1273 kJ/mol.
The carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.
If 14.5 kJ of heat were added to 485 g of liquid water, how much would its temperature increase?
Insoluble AgCl(s) precipitates when solutions of AgNO3(aq) and NaCl(aq) are mixed. AgNO3(aq) + NaCl(aq) AgCl(s) + NaNO3(aq) rH = ? To measure the energy evolved in this reaction, 250. mL of 0.16 M AgNO3(aq) and 125 mL of 0.32 M NaCl(aq) are mixed in a coffee-cup calorimeter. The temperature of the mixture rises from 21.15 C to 22.90 C. Calculate the enthalpy change for the precipitation of AgCl(s), in kJ/mol. (Assume the density of the solution is 1.0 g/mL and its specific heat capacity is 4.2 J/g K.)