Please predict the outcome of each reaction below: Type you answer as a letter: A, B, ..., or F. Problem 1: https://doi.org/10.1021/ol101705j Answer to Problem 1: Hint 1. Assume the reaction can ONLY occur at the MOST ELECTRON RICH double bond. Hint 2. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer. 1 equivalent m-CPBA ? A H B C D E F

Please predict the outcome of each reaction below: Type you answer as a letter: A, B, ..., or F. Problem 1: https://doi.org/10.1021/ol101705j Answer to Problem 1: Hint 1. Assume the reaction can ONLY occur at the MOST ELECTRON RICH double bond. Hint 2. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer. 1 equivalent m-CPBA ? A H B C D E F

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter8: Haloalkanes, Halogenation, And Radical Reactions

Section: Chapter Questions

Problem 8.28P

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Draw a curved arrow mechanism for the substitution reaction that will occur with the alkyl halide and nucleophile below, adding steps as necessary. Be sure to include all nonbonding electrons and all nonzero formal charges, and show all species that react or are formed in this reaction.
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Copy the given reaction and show the mechanism by supplying the appropriate curved arrows. Also, identify the general type of reaction mechanism (polar or non-polar). For polar reaction mechanisms, label the nucleophile and the electrophile. :0: :0 O.. H. HÖ: Hö:
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Draw the full electron pushing mechanism for the reaction depicted including ALL intermediates (with lone pairs and formal charges). Clearly label the electrophile and nucleophile in each step where appropriate.
ited Draw both resonance structures of the most stable carbocation intermediate in the reaction shown. od m... • You do not have to consider stereochemistry. . Do not include anionic counter-ions, e.g., I', in your answer. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom Separate resonance structures using the → symbol from the drop-down menu. ● CH4 + ? HBr
(Explain all point of question with proper type the answer) .
In Part 1 add the curved arrows to the nucleophilic acyl substitution reaction mechanism. In Part 2, answer the multiple-choice question about the reaction in Part 1. Part 1 See Periodic Table O See Hint :ö: :Br: Add the missing curved arrow notation. 20 F CI Br I Part 2 Which statement is most correct regarding the equilibrium for the above reaction? Choose one: O The equilibrium favors the right (i.e., Kea > 1) because acetate is a better leaving group than bromide. O The equilibrium favors the right (i.e., Keg > 1) because bromide is a better leaving group than acetate. O The equilibrium favors the left (i.e. Keg « 1) because acetate is a better leaving group than bromide. O The equilibrium favors the left (i.e., Keg« 1) because bromide is a better leaving group than acetate.
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For the reaction given below, draw a mechanism (curved arrows) and then predict which side of the reaction is favoured under equilibrium conditions. Include lone pairs and formal charges. Predict which side of the reaction is favored under equilibrium conditions, and explain your choice. a. the reactants are favored, because the negative charge on the electronegative oxygen atom is more stable (making it the stronger base). b. the products are favored, because the negative charge on the electronegative oxygen atom is more stable (making it the weaker base). c. the products are favored, because the negative charge on the large sulfur atom is more stable (making it the weaker base). d. the reactants are favored, because the negative charge on the large sulfur atom is more stable (making it the stronger base).
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027 In Part 1 add the curved arrows to the nucleophilic acyl substitution reaction mechanism. In Part 2, answer the multiple-choice question about the reaction in Part 1. Part 1 4 See Periodic Table O See Hint :0: :Br: Add the missing curved arrow notation. S CI Br Part 2 Which statement is most correct regarding the equilibrium for the above reaction? Choose one: O The equilibrium favors the right (i.e., Kea > 1) because acetate is a better leaving group than bromide. O The equilibrium favors the right (i.e., Kea > 1) because bromide is a better leaving group than acetate. O The equilibrium favors the left (i.e., Keq« 1) because acetate is a better leaving group than bromide. O The equilibrium favors the left (i.e., Keg 1) because bromide is a better leaving group than acetate. +