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- The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?6) Give the products of each of the following reactions. a) b) d) H Li, NH3 CH3CH₂OH xo Na₂Cr₂O7 H₂O, H₂SO4, A H₂O LI, NH3 CH₂CH₂OHnane Draw the principal products of the following eactic (a) H. CH¿CH2CH, HCH,C H. Br (b) NBS hv. CC (c) (d) COOH CH,CH,OH
- Predict the major product of the following reaction and draw it in the space provided. 1) NAOMe Br 2) Meo Ome Br 3) NaOt-Bu 4) HCI, H₂O, heatDraw the organic product(s) of the following reaction. CH3 H3C-C-CEC-H CH3 NaOC2Hs / CH5OH 1 eq. NANH2, NH3(1) CH;CH,CH,CH2-Br H-CEC-H H;C CH-Br H3C 1 eq. NaNH2, NH3() H3C-CEC-HK app.101edu.co Lepadiformine is a cytotoxic marine alkaloid that has cardiovascular biological activity. Draw the product of this key SN2 reaction (shown below) used in the synthesis of lepadiformine. Use wedge and dash bonds to indicate stereochemistry where appropriate. Ignore inorganic byproducts. Br Si e H Draw SN2 product THF
- Q17. Compound 1 can undergo an intramolecular reaction to give cyclic product 2. Using curly arrows, show the mechanism of this reaction – note that the mechanism involves more than one elemental step - and draw the structure of 2; chemical formula is provided as guidance. H2N. C5H9NO CH;OH 2Identify the following pericyclic reaction; explain the course and stereochemistry of the reaction.Propose a mechanism for this reaction. || » CH3COCH=CH, H,SO4 HC=CH + CH3COH H9SO4 Acetylene Acetic acid Vinyl acetate Vinyl acetate is the monomer for the production of poly(vinyl acetate), the major use of which is as an adhesive in the construction and packaging industry, but it is also used in the paint and coatings industry.
- Predict the product. CH₂ JOH CH₂N₂₂ & CH₂ LOCH₂CH₂ DA3 • THE BH CO CHILE Predict the products. If No reaction, write NR. • LOCH " CH₂CH₂M. Br (Ences), 2) Ht o lolot 요요 CHÍNHPredict the major product of the following reaction. (CH3)3C-OOH LOH TI[OCH(CH3)214 (-)-DET Dom -OH 11 OH Io ||| Ø OH IVWhen phosgene is treated with excess methanol, a product is formed whose "H NMR spectrum shows one peak-a singlet at 3.8 ppm. Provide a complete, CH,OH ? CI CI detailed mechanism for this reaction. Phosgene