The compound oxygen difluoride is quite reactive, giving oxygen and HF when treated with water: OF2(g) + H2O(g) → O2(g) + 2HF(g) ΔE°rxn = –318 kJ Using bond energies, calculate the bond dissociation energy of the O–F bond in OF2. Average Bond Energies (kJ/mol) Picture O–F bond dissociation energy = _____kJ/mol

Introduction to General, Organic and Biochemistry
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Chapter3: Chemical Bonds
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Problem 3.104P
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The compound oxygen difluoride is quite reactive, giving oxygen and HF when treated with water:

OF2(g) + H2O(g) → O2(g) + 2HF(g)
ΔE°rxn = –318 kJ

Using bond energies, calculate the bond dissociation energy of the O–F bond in OF2.

Average Bond Energies (kJ/mol)

Picture

O–F bond dissociation energy = _____kJ/mol

 
Single Bonds
Multiple Bonds
432
391
149
208
H-H
N-H
C=C
614
H-F
565
N-N
160
-CI
C=C
839
H-CI
427
N-F
272
-Br
175
0=0
495
H-Br
363
N-CI
200
C=0*
745
H-I
295
N-Br
243
S-H
347
C=0
1072
S-F
S-CI
N-O
201
327
N=O
607
C-H
413
O-H
467
253
N=N
418
C-C
347
O-O
146
S-Br
218
N=N
941
C-N
305
O-F
190
S-S
266
C=N
891
C-O
358
0-CI
203
C=N
615
C-F
485
O-I
234
Si-Si
340
C-CI
339
Si-H
393
C-Br
276
F-F
154
Si-C
360
C-I
240
F-CI
253
Si-O
452
C-S
259
F-Br
237
CI-CI
239
CI-Br
218
Br-Br
193
*C=O(in CO,) = 799
Transcribed Image Text:Single Bonds Multiple Bonds 432 391 149 208 H-H N-H C=C 614 H-F 565 N-N 160 -CI C=C 839 H-CI 427 N-F 272 -Br 175 0=0 495 H-Br 363 N-CI 200 C=0* 745 H-I 295 N-Br 243 S-H 347 C=0 1072 S-F S-CI N-O 201 327 N=O 607 C-H 413 O-H 467 253 N=N 418 C-C 347 O-O 146 S-Br 218 N=N 941 C-N 305 O-F 190 S-S 266 C=N 891 C-O 358 0-CI 203 C=N 615 C-F 485 O-I 234 Si-Si 340 C-CI 339 Si-H 393 C-Br 276 F-F 154 Si-C 360 C-I 240 F-CI 253 Si-O 452 C-S 259 F-Br 237 CI-CI 239 CI-Br 218 Br-Br 193 *C=O(in CO,) = 799
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