used to scrub SO2 gas from the exhaust gases of powerplants. One possible reaction gives hydrated calcium sulfite and anotherhydrated calcium sulfate.The balanced equations for the two reactions are: CaCO3 (s) + SO2 (g) + ½ H2O (l) ⇌ CaSO3∙½H2O (s) + CO2 (g) CaCO3 (s) + SO2 (g) + ½ H2O (l) + ½ O2 (g) ⇌ CaSO4∙½H2O (s) + CO2 (g) Which of the two reactions will be more product favoured?Wet limestone is used to scrub SO2 gas from the exhaust gases of powerplants. One possible reaction gives hydrated calcium sulfite and anotherhydrated calcium sulfate.The balanced equations for the two reactions are: CaCO3 (s) + SO2 (g) + ½ H2O (l) ⇌ CaSO3∙½H2O (s) + CO2 (g) CaCO3 (s) + SO2 (g) + ½ H2O (l) + ½ O2 (g) ⇌ CaSO4∙½H2O (s) + CO2 (g) Calculate rGº for the reaction CaSO3∙½H2O (s) + ½ O2 (g) ⇌ CaSO4∙½H2O (s)
used to scrub SO2 gas from the exhaust gases of powerplants. One possible reaction gives hydrated calcium sulfite and anotherhydrated calcium sulfate.The balanced equations for the two reactions are: CaCO3 (s) + SO2 (g) + ½ H2O (l) ⇌ CaSO3∙½H2O (s) + CO2 (g) CaCO3 (s) + SO2 (g) + ½ H2O (l) + ½ O2 (g) ⇌ CaSO4∙½H2O (s) + CO2 (g) Which of the two reactions will be more product favoured?Wet limestone is used to scrub SO2 gas from the exhaust gases of powerplants. One possible reaction gives hydrated calcium sulfite and anotherhydrated calcium sulfate.The balanced equations for the two reactions are: CaCO3 (s) + SO2 (g) + ½ H2O (l) ⇌ CaSO3∙½H2O (s) + CO2 (g) CaCO3 (s) + SO2 (g) + ½ H2O (l) + ½ O2 (g) ⇌ CaSO4∙½H2O (s) + CO2 (g) Calculate rGº for the reaction CaSO3∙½H2O (s) + ½ O2 (g) ⇌ CaSO4∙½H2O (s)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter17: Spontaneity, Entropy, And Free Energy
Section: Chapter Questions
Problem 107CWP: Given the thermodynamic data below, calculate S and Ssurr for the following reaction at 25C and 1...
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s used to scrub SO2 gas from the exhaust gases of powerplants. One possible reaction gives hydrated calcium sulfite and anotherhydrated calcium sulfate.The balanced equations for the two reactions are: CaCO3 (s) + SO2 (g) + ½ H2O (l) ⇌ CaSO3∙½H2O (s) + CO2 (g) CaCO3 (s) + SO2 (g) + ½ H2O (l) + ½ O2 (g) ⇌ CaSO4∙½H2O (s) + CO2 (g) Which of the two reactions will be more product favoured?Wet limestone is used to scrub SO2 gas from the exhaust gases of powerplants. One possible reaction gives hydrated calcium sulfite and anotherhydrated calcium sulfate.The balanced equations for the two reactions are: CaCO3 (s) + SO2 (g) + ½ H2O (l) ⇌ CaSO3∙½H2O (s) + CO2 (g) CaCO3 (s) + SO2 (g) + ½ H2O (l) + ½ O2 (g) ⇌ CaSO4∙½H2O (s) + CO2 (g) Calculate rGº for the reaction CaSO3∙½H2O (s) + ½ O2 (g) ⇌ CaSO4∙½H2O (s)
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Wet limestone is used to scrub SO2 gas from the exhaust gases of powerplants. One possible reaction gives hydrated calcium sulfite and anotherhydrated calcium sulfate.The balanced equations for the two reactions are:
CaCO3 (s) + SO2 (g) + ½ H2O (l) ⇌ CaSO3∙½H2O (s) + CO2 (g) CaCO3 (s) + SO2 (g) + ½ H2O (l) + ½ O2 (g) ⇌ CaSO4∙½H2O (s) + CO2 (g)
Which of the two reactions will be more product favoured?Wet limestone is used to scrub SO2 gas from the exhaust gases of power
plants. One possible reaction gives hydrated calcium sulfite and another
hydrated calcium sulfate.
The balanced equations for the two reactions are:
CaCO3 (s) + SO2 (g) + ½ H2O (l) ⇌ CaSO3∙½H2O (s) + CO2 (g)
CaCO3 (s) + SO2 (g) + ½ H2O (l) + ½ O2 (g) ⇌ CaSO4∙½H2O (s) + CO2 (g)
Calculate rGº for the reaction
CaSO3∙½H2O (s) + ½ O2 (g) ⇌ CaSO4∙½H2O (s)
Transcribed Image Text:Thermodynamic quantities for Selected Substances at 298.15 K (25°C)
AHP
AGO
s°
(kJ/mol)
(kJ/mol)
(9/mol•K)
CasO3-%H2O (s)
-1311.7
121.3
CasOa-%H2O (s)
-1574.65
134.8
CaCO3 (s)
-1207.6
-1129.16
91.7
SO2 (g)
-296.84
-300.13
248.21
H20 (I)
-285.83
-237.15
69.95
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