What would cause a difference in the calculated dipole moment compared with an experimental value? Thank you :)

Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter7: Chemical Bonding And Molecular Geometry
Section: Chapter Questions
Problem 102E: The molecule XCl2 has a dipole moment. Is X beryllium or sulfur?
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What would cause a difference in the calculated dipole moment compared with an experimental value? Thank you :)

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