Inorganic Chemistry
Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
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Chapter 2, Problem 2.30P

A sample calculation in this chapter showed that, according to Slater’s rules, a 3d electronof nickel has a higher effective nuclear charge than a 4s electron. Is the same true for early first-row transition metals? Using Slater’s rules, calculate S and Z* for 4s and 3d electrons of Sc andTi. and comment on the similarities or differences with Ni.

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15. Using Slater's Rules, determine the Z* for a. a 3p electron in P, S, CI, and Ar. b. a 2p electron in O2, F;, Na*, Mg2* c. a 4s and 3d electron of Cu. Which type of electron is more likely to be lost when copper forms a positive ion, Cu*?
3. Using Slater's Rules, determine the Zem for a 4d electron in Yttrium and a 5s electron in the same neutral atom. Which one would be more difficult to ionize? Do your results agree with the actual predicted electron configuration of the Yion? Carry out the same analysis for Ag and Ag list of
Usina Slater's Rules. predict Zeff for the following electrons (convert your fill - order configurations to energy-level order): a.) the last p -type electron in Lead (Pb); b.) the last f-type electron in Holmium (Ho) c.) an n 3 p-type electron in Ruthenium (Ru).

Chapter 2 Solutions

Inorganic Chemistry

Ch. 2 - The transition from the n=7 to the n=2 level of...Ch. 2 - Emissions are observed at wavelengths of 383.65...Ch. 2 - What is the least amount of energy that can be...Ch. 2 - Hydrogen atom emission spectra measured from the...Ch. 2 - The Rydberg constant equation has two terms that...Ch. 2 - For the 3pz and 4dxz hydrogen-like atomic...Ch. 2 - Repeat the exercise in Problem 2.7 for the 4s and...Ch. 2 - Repeat the exercise in Problem 2.7 for the 5s and...Ch. 2 - The 4fz(x2y2) orbital has the angular function...Ch. 2 - Prob. 2.13PCh. 2 - The label for an fz2 orbital, like that for a dz2...Ch. 2 - a. Determine the possible values for the l and ml...Ch. 2 - a. What are the values of quantum numbers I and n...Ch. 2 - a. At most, how many electrons in an atom can have...Ch. 2 - Determine the Coulombic and exchange energies for...Ch. 2 - Prob. 2.19PCh. 2 - Prob. 2.20PCh. 2 - What states are possible for a d3 configuration?...Ch. 2 - Provide explanations of the following phenomena:...Ch. 2 - Give electron configurations for the following:...Ch. 2 - Predict the electron configurations of the...Ch. 2 - Radial probability plots shed insight on issues of...Ch. 2 - Briefly explain the following on the basis of...Ch. 2 - Briefly explain the following on the basis of...Ch. 2 - a. Which 2+ ion has two 3d electrons? Which has...Ch. 2 - A sample calculation in this chapter showed that,...Ch. 2 - Ionization energies should depend on the effective...Ch. 2 - Prepare a diagram such as the one in Figure (a)...Ch. 2 - Why are the ionization energies of the alkali...Ch. 2 - The second ionization of carbon (C+C2++e) and the...Ch. 2 - Prob. 2.35PCh. 2 - Prob. 2.36PCh. 2 - The second ionization energy involves removing an...Ch. 2 - Prob. 2.38PCh. 2 - On the basis of electron configurations, explain...Ch. 2 - a. The graph of ionization energy versus atomic...Ch. 2 - The second ionization energy of He ¡s almost...Ch. 2 - The size of the transition-metal atoms decreases...Ch. 2 - Predict the largest and smallest radius in each...Ch. 2 - Select the best choice, and briefly indicate the...Ch. 2 - Select the best choice, and briefly indicate the...Ch. 2 - There are a number of Web sites that display...Ch. 2 - Prob. 2.47P
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