Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337399425
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 20, Problem 146CP
Interpretation Introduction
Interpretation:
The
Concept Introduction:
Esterification is a
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Salicylic acid is added into a test tube, followed by methanol and sulfuric acid as the catalyst. It is heated for 10-15 minutes and poured into a beaker with crushed ice. This is the esterification of Oil of wintergreen. Write the complete reaction equation and describe the odor of the reactants (salicylic acid and methanol) and the products (oil of wintergreen).
The boiling point of propyl propanoate is 123oC. To make an ester that has a higher boiling point, which alcohol should you react with propanoic acid?
What is the atomic formula of ribitol?
1. a) Use structures to show the formation of an ester via a condensation reaction. Specifically:
First draw structures of palmitic acid and methanol
Then draw the ester that would form when this acid and alcohol are heated with HCl as an acid catalyst.
●
b) In Part A of Lab #7, how will you know that you've successfully condensed the various acid and alcohol functional
groups to form ester linkages?
c) Which of the condensation reagents do you need to handle with care, and why?
Chapter 20 Solutions
Introductory Chemistry: A Foundation
Ch. 20.2 - Exercise 20.1 Give the molecular formulas for the...Ch. 20.4 - Exercise 20.2 Name the following molecules. a. b.Ch. 20.4 - Exercise 20.3 Write the structural formula for...Ch. 20.5 - Petroleum is a very valuable raw material for the...Ch. 20.7 - Exercise 20.4 Name the following molecules. a. b.Ch. 20.9 - Prob. 20.5SCCh. 20.11 - Prob. 20.6SCCh. 20.14 - Prob. 20.7SCCh. 20 - What is meant by the term “unsaturated...Ch. 20 - Prob. 2ALQ
Ch. 20 - Prob. 3ALQCh. 20 - How many different possible “tetramethylbenzenes”...Ch. 20 - For the general formula C6H14O, draw the...Ch. 20 - Prob. 6ALQCh. 20 - Prob. 1QAPCh. 20 - Your roommate, a chemistry major, claims to have...Ch. 20 - Prob. 3QAPCh. 20 - How many electron pairs are shared when a triple...Ch. 20 - Prob. 5QAPCh. 20 - Prob. 6QAPCh. 20 - Prob. 7QAPCh. 20 - Prob. 8QAPCh. 20 - Prob. 9QAPCh. 20 - . The chains in normal alkanes are not really...Ch. 20 - Prob. 11QAPCh. 20 - Prob. 12QAPCh. 20 - . Give the name of each of the following...Ch. 20 - Prob. 14QAPCh. 20 - . What are structural isomers? Which is the...Ch. 20 - Prob. 16QAPCh. 20 - Prob. 17QAPCh. 20 - Prob. 18QAPCh. 20 - Prob. 19QAPCh. 20 - Prob. 20QAPCh. 20 - . What is an alkyl group? How is a given alkyl...Ch. 20 - . When naming alkanes, find the longest continuous...Ch. 20 - Prob. 23QAPCh. 20 - . When naming alkanes, the alkyl groups are listed...Ch. 20 - . Give the systematic name for each of the...Ch. 20 - . Give the systematic name for each of the...Ch. 20 - Prob. 27QAPCh. 20 - Prob. 28QAPCh. 20 - Prob. 29QAPCh. 20 - Prob. 30QAPCh. 20 - . What is pyrolytic cracking, and why is the...Ch. 20 - Prob. 32QAPCh. 20 - . Explain why alkanes are relatively unreactive.Ch. 20 - Prob. 34QAPCh. 20 - . Indicate the missing molecule in each of the...Ch. 20 - Prob. 36QAPCh. 20 - Prob. 37QAPCh. 20 - Prob. 38QAPCh. 20 - Prob. 39QAPCh. 20 - Prob. 40QAPCh. 20 - Prob. 41QAPCh. 20 - Prob. 42QAPCh. 20 - Prob. 43QAPCh. 20 - Prob. 44QAPCh. 20 - Prob. 45QAPCh. 20 - Prob. 46QAPCh. 20 - Prob. 47QAPCh. 20 - Prob. 48QAPCh. 20 - Prob. 49QAPCh. 20 - . Benzene exhibits resonance Explain this...Ch. 20 - . How is a monosubstituted benzene named? Give the...Ch. 20 - Prob. 52QAPCh. 20 - Prob. 53QAPCh. 20 - . What do the prefixes ortho-, meta-, and para-...Ch. 20 - Prob. 55QAPCh. 20 - Prob. 56QAPCh. 20 - Prob. 57QAPCh. 20 - Prob. 58QAPCh. 20 - . What functional group characterizes an alcohol?...Ch. 20 - Prob. 60QAPCh. 20 - . Give the systematic name for each of the...Ch. 20 - . Is 1-pentanol a primary, secondary, or tertiary...Ch. 20 - . Why is methanol sometimes called wood alcohol?...Ch. 20 - Prob. 64QAPCh. 20 - . Write the equation for the synthesis of ethanol...Ch. 20 - . What is the simplest aromatic alcohol commonly...Ch. 20 - Prob. 67QAPCh. 20 - Prob. 68QAPCh. 20 - Prob. 69QAPCh. 20 - Prob. 70QAPCh. 20 - Prob. 71QAPCh. 20 - Prob. 72QAPCh. 20 - Prob. 73QAPCh. 20 - Prob. 74QAPCh. 20 - Prob. 75QAPCh. 20 - Prob. 76QAPCh. 20 - Prob. 77QAPCh. 20 - Prob. 78QAPCh. 20 - Prob. 79QAPCh. 20 - Prob. 80QAPCh. 20 - Prob. 81QAPCh. 20 - . Draw a structural formula for each of the...Ch. 20 - Prob. 83QAPCh. 20 - Prob. 84QAPCh. 20 - Prob. 85QAPCh. 20 - Prob. 86QAPCh. 20 - Prob. 87QAPCh. 20 - Prob. 88QAPCh. 20 - Prob. 89APCh. 20 - Prob. 90APCh. 20 - Prob. 91APCh. 20 - Prob. 92APCh. 20 - Prob. 93APCh. 20 - . The systematic names of all saturated...Ch. 20 - Prob. 95APCh. 20 - Prob. 96APCh. 20 - Prob. 97APCh. 20 - Prob. 98APCh. 20 - Prob. 99APCh. 20 - . With very reactive agents, such as the halogen...Ch. 20 - . Alkenes and alkynes are characterized by their...Ch. 20 - Prob. 102APCh. 20 - Prob. 103APCh. 20 - Prob. 104APCh. 20 - Prob. 105APCh. 20 - Prob. 106APCh. 20 - Prob. 107APCh. 20 - Prob. 108APCh. 20 - Prob. 109APCh. 20 - Prob. 110APCh. 20 - Prob. 111APCh. 20 - Prob. 112APCh. 20 - Prob. 113APCh. 20 - Prob. 114APCh. 20 - Prob. 115APCh. 20 - . Give the systematic name for each of the...Ch. 20 - Prob. 117APCh. 20 - Prob. 118APCh. 20 - Prob. 119APCh. 20 - Prob. 120APCh. 20 - Prob. 121APCh. 20 - Prob. 122APCh. 20 - Prob. 123APCh. 20 - Prob. 124APCh. 20 - Prob. 125APCh. 20 - Prob. 126APCh. 20 - Prob. 127APCh. 20 - Prob. 128APCh. 20 - Prob. 129APCh. 20 - Prob. 130APCh. 20 - Prob. 131APCh. 20 - . Write the formula for the missing reactant or...Ch. 20 - Prob. 133APCh. 20 - Prob. 134APCh. 20 - . Name each of the following aromatic or...Ch. 20 - Prob. 136APCh. 20 - Prob. 137APCh. 20 - Prob. 138APCh. 20 - Prob. 139APCh. 20 - Prob. 140APCh. 20 - Prob. 141APCh. 20 - . Name each of the following alkanes....Ch. 20 - Prob. 143CPCh. 20 - Prob. 144CPCh. 20 - Prob. 145CPCh. 20 - Prob. 146CPCh. 20 - Prob. 147CP
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- In an esterification reaction, a carboxylic acid reacts with an excess of alcohol in acidic conditions to form an ester. Draw the structure of the ester product in the reaction between pentanoic acid and 1‑propanol.arrow_forward. The following chemical reactants produce the ester ethylethanoate (C4H8O2):C2H6O + CH3COOHWhat type of reaction occurs to make ethyl ethanoate?a. condensationb. hydrolysisc. combustiond. acid-base reactionarrow_forwardTRUE OR FALSE. The hydrolysis of an ester can also be catalyzed by the presence of a strong base. The base-catalyzed hydrolysis of an ester is called saponification. TRUE OR FALSE. Hydrolysis is a reaction in which a bond is broken by the addition of a water molecule without the presence of heat. TRUE OR FALSE. Esterification is a condensation reaction.arrow_forward
- Acid anhydride Carboxylic Acid H₂C CH₂OH H₂O CH,OH CH3 Ester H₂C O CH₂OH 1. CH₂MgBr 2. H₂O* Acid chloride CH,CH,NH, Tertiary alcohol Amidearrow_forwardEster formation and ester hydrolysis are exactly the same reaction only written in reverse. General reaction of ester formation: H*, heat R—с—он + Н—о—R' R—с—о-R' + H,O carboxylic acid alcohol carboxylic or phenol ester General reaction of ester hydrolysis: || R—с—OR' + H—оН R—с—оН +R—ОH ester carboxylic acid alcohol or phenol What determines which direction the reaction proceeds and what actually forms? o the boiling point of the carboxylic acid o the presence (or absence) of heat as well as the concentration of reactants and products o the molecular weight of reactants and products o the presence (or absence) of heat as well as the catalystarrow_forwardA carboxylic acid reacts with water to form a carboxylate ion and H₂O+. Complete the reaction. reaction: CH₂COOH + H₂O= Write the IUPAC name of the carboxylate ion formed in the reaction. IUPAC name:arrow_forward
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- Which of the following statements describes the thermodynamic directionality of this reaction? Select an answer and submit. For keyboard navigation, use the up/down arrow keys to select an answer. a Reactant-favored only at low temperatures b Reactant-favored at all temperatures с Product-favored only at low temperatures d Product-favored at all temperaturesarrow_forwardis butane-2,3-dione soluble in water? HCl? NaOH? NaHCO3?arrow_forwardWhat are the generic structures for carboxylic acids and esters? Write a structure for a specific carboxylic acid and ester.arrow_forward
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