Experiment 8: The Copper Cycle
Purpose
The main goal of this experiment was to observe series of reactions that convert a piece of copper metal, via several different copper-containing compounds, back into its original elemental form. The data collected was the striking color changes along with their relevant chemical equations. The data was collected while keeping a close eye on the experiment the whole time. The data recorded was used to see the different changes involved with a piece of copper metal. The copper was weighed and heated multiple times throughout the experiment
Procedure
CHE 131 Experiment 8, General Chemistry 1 Lab, 1 Quarter 2015-2016, DePaul University. [Online] https://www.d2l.depaul.edu (November 09, 2015).
Data and Results
Table 1: Summary of Raw Data
Starting with the mass of the copper wire, this table recorded the weight (g) along with observations that occurred throughout the procedure. At the beginning of the procedure, 4.0 mL of concentrated nitric acid, HNO3 (16 M), was added to a 50 mL beaker containing a pre-cut, pre-cleaned piece of Copper (Cu) wire. A lively reaction occurred as the Cu was disolved, forming a brown, harmful gas inside the beaker. The gas was nitric oxide. To better describe the observation is the chemical equation,
Cu(s) + 4 HNO3(aq) —> Cu(NO3)2(aq) + 2 NO2(g) + 2 H2O(l), where nitric acid dissolved copper and left the products, copper (II) nitrate, Cu(NO3)2, water, and nitrogen dioxide (NO2). After a while the gas
In the experiment, What Goes Around Comes Around, the element copper was put through a series of chemical changes to observe whether or not the final copper precipitate had the same mass as the initial mass of the copper. The purpose of this lab is to prove the Law of Conservation of Mass, which states that mass cannot be created nor destroyed. In the experiment, if the final mass of the copper precipitate is equal to the initial mass of copper, this law is proven because the copper was not destroyed in the chemical reactions nor was it created. Copper was first combined with the compounds nitric acid(HNO3), water(H2O), and sodium hydroxide(NaOH). This mixture was first chemically separated using heat to boil out the water. The aqueous solution
In the fume hood, 3 mL of a 15 M concentrated ammonia solution was added to each volumetric flask. The flasks were swirled until all solids were dissolved. Each flask was diluted to volume with distilled water, covered with Parafilm, and mixed. The concentration (in g/L) of Cu2+ was calculated in each of the six standard solutions.
The purpose of the experiment is to cycle solid copper through a series of five reactions. At different stages of the cycle, copper was present in different forms. First reaction involves reaction between the copper and nitric acid, and copper changed from elemental state to an aqueous. The second reaction converted the aqueous Cu2+ into the solid copper (2) hydroxide. In the third reaction Cu(OH)2 decomposed into copper 2 oxide and water when heated. When solid CuO reacted with sulfuric acid, the copper returned to solution as an ion (Cu2+). The cycle of reactions was completed with the reaction where elemental copper was regenerated by Zn and Cu
The mole is a convenient unit for analyzing chemical reactions. Avogadro’s number is equal to the mole. The mass of a mole of any compound or element is the mass in grams that corresponds to the molecular formula, also known as the atomic mass. In this experiment, you will observe the reaction of iron nails with a solution of copper (II) chloride and determine the number of moles involved in the reaction. You will determine the number of moles of copper produced in the reaction of iron and copper (II) chloride, determine the number of moles of iron used up in the reaction of iron and copper (II) chloride, determine the ratio of moles of iron to moles of copper, and determine the number of atoms and formula units involved in
The Cu Later lab experiment is designed to allow you to practice lab skills in implementing and performing a series of reactions. Specifically, four types of chemical reactions will occur: oxidation/reduction; double replacement; single replacement; and decomposition. You will begin with a known amount of copper metal, which, after progressing through several steps, is reproduced. In this experiment you will observe and record the various changes such as heat, color changes, and production that occur. This procedure is used to observe some chemical reactions of copper and its compounds while also performing the lab appropriately as to retain the copper as much as
In this experiment you will observe some physical and some chemical changes. You will observe that energy must be used to start some chemical reactions, and that it is produced in others.
Eleven mystery test tubes labeled from K-1 to K-11 contained: 6M H2SO4, 6M NH3, 6M HCl, 6M NaOH, 1M NaCl, 1M Fe(NO3)3, 1M NiSO4, 1M AgNO3, 1M KSCN, 1M Ba(NO3)2, 1M Cu(NO3)2 respectively. The contents of the test tubes were determined by chemical experiments. Solution K-1 contained NiSO4 because when solution K-9, ammonia which was identified by its pungent odor, was added, an inky dark blue color was made. Iron (Fe (NO3)3) was determined to be in test tube K-2. KSCN was found in test tube K-11 since Fe (NO3)3 and KSCN makes a bloody color when mixed together. Flame tests were conducted in which K-8
-If the copper metal is submerged in the silver nitrate solution then in reaction, a pure, solid (Ag) silver product is created with an excess of (Cu (NO3)2) copper (II) aqueous liquid because a single displacement reaction occurs where the balance equation is then
Before the synthesis of the Copper Iodine Compound, the identities provided (CuNO3)2 and Nal weighed 1.65 g and 4.7 g, respectively. After being weighed, the (CuNO3)2 exhibited a blue color, while the Nal, through observation, was a white color. However, when both identities were combined, the product turned into a brown and red rocky material. Once 20 mL of deionized water was added, the product quickly turned pale pink paste. After the solution was repeatedly washed with a total of an additional 100 mL of deionized water, the product was powdery and pink with small grains, and was left to air-dry. Once the product was air dried, it was observed to be a pale pink color, while the filter paper was stiff as the product was hard and dry. Therefore, the solid was scraped off onto a recrystallizing dish. However, the mass of an empty recrystallizing dish needed to be recorded in order to compare how much of the synthesized copper iodide was obtained. Within this case, the empty recrystallizing dish used weighed 32.01 g, the product on the empty dish weighed 1.03 g, having a total weight of 33.04 g.
The Copper Cycle is a popular experiment used to determine if an element, in this instance, copper, reverts to its elemental form after a chain of reactions. This experiment is very dangerous because of the reactions between the strong acids and bases. In this experiment I performed a series of reactions starting with copper metal and nitric acid to form copper (II) nitrate. Then I reacted copper and several other solutions such as, sodium hydroxide, sulfuric acid, ammonium hydroxide, and hydrochloric acid to form precipitates. In conclusion my percent recovery
Experimental approach: In the first reaction, copper metal turnings oxidize when put in contact with nitric acid and become copper nitrate.
The lab performed required the use of quantitative and analytical analysis along with limiting reagent analysis. The reaction of Copper (II) Sulfate, CuSO4, mass of 7.0015g with 2.0095g Fe or iron powder produced a solid precipitate of copper while the solution remained the blue color. Through this the appropriate reaction had to be determined out of the two possibilities. Through the use of a vacuum filtration system the mass of Cu was found to be 2.1726g which meant that through limiting reagent analysis Fe was determined to be the limiting reagent and the chemical reaction was determined to be as following:-
CHE 133 Experiment 3, General Chemistry II Lab, Spring Quarter 2014-2015, DePaul University. [Online] https://www.d2l.depaul.edu (accessed April 25, 2015)
First, we assembled a fume hood by using a ring stand, a hot plate, a 50 ml beaker, an iron ring to secure the beaker, and a plastic funnel hooked up to rubber tubing and an aspirator. A hose from the sink was then connected to the aspirator and the pressure that the water created allowed the fume hood to remove whatever excess gas was given off during the experiment. In cycle step one, we placed approximately 250 mg of copper into the 50 ml beaker then added 6 ml of HNO_3. We then heated the plate to 10° C until the reaction took place to save time. We would recommend heating the plate initially at 20 C in order to speed up the experiment. The solution was at 11 ml total at the end of step1. In cycle step 2, we
Copper is a pollutant of concern due to its toxic effects on aqua- ecosystems, its ability to accumulate in sediments and tissues of living organisms, and its non-biodegradable nature. Copper is widely used in industries such as manufacturing, building and construction, electrical and electronic, and industrial machinery and equipment production [2]. The future availability of Cu may not be guaranteed because of its increasing demand and shrinking reserves [2, 3]. Therefore, it is required to remove/recover Cu from industrial wastewaters [4]. The Cu removal/recovery from wastewaters is admirable from both health and economic point of views.