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Investigating the Kinetics of the reaction between Iodide ions and Peroxodisulphate (VI) ions (entire plan)

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Investigating the Kinetics of the reaction between Iodide ions and Peroxodisulphate (VI) ions

By the use of an Iodine clock reaction I hope to obtain the length of time taken for Iodine ions (in potassium iodide) to react fully with Peroxodisulphate ions (in potassium Peroxodisulphate). I will do three sets of experiments changing first the concentration of iodide ions, then the concentration of Peroxodisulphate ions and finally the temperature of the solution in which the reaction is taking place. From these results, I hope to draw conclusions as to the effects of these changes to the environment of the reaction on the rate and also determine the order of the reaction and the activation enthalpy.

Background information

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Effect of Temperature
A basic law of physical chemistry is that an increase in temperature causes an increase in the rate of any reaction. As the collision theory states, for a reaction to take place the particles need to collide. If the temperature is increased, each particle has greater kinetic energy transferred from the heat energy, and therefore is moving faster (the average speed of molecules is proportional to the square root of the absolute temperature.) The faster the particles are moving, the more likely they are to collide and therefore the faster the reaction. Also, the more energy transferred to each particle due to increased temperature the more likely it is to surmount the activation enthalpy and again the higher the number of effective collisions. As a general rule, the rate of a reaction doubles for every increase of 10K in temperature.

The diagram below demonstrates the effect of temperature on the rate of a reaction. Despite the initial increase in the energy of particles of a lower temperature, one can see that those at a higher temperature eventually surpass and lead to an overall higher amount of particles with energy higher than the activation enthalpy and therefore a greater number of effective collisions.

The exact relationship between temperature and rate of reaction was first proposed by a Swedish chemist called Arrhenius in

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