preview

Macromolecules: What Is Polymers?

Better Essays

Polymers
Polymers are large molecules with large molar masses and are composed of many repeating subunits. Also referred to as macromolecules, polymers both synthetic and natural have a broad range of properties which play a vital role in everyday life. Polymers range from naturally occurring biopolymers such as DNA, proteins, cellulose and starches to synthetic plastics including polystyrene and polyethylene (Shakhashiri). Polymers are synthesised using a chemical process known as polymerisation, where individual molecules called monomers are reacted to form chains or three dimensional networks.
A look at the history of polymers reveals that many of the first discoveries were accidental. Since these discoveries, a whole new area of chemistry …show more content…

Not long after the original discovery, the first production plant came into operation in 1939, making polyethylene for use in insulating radar cables. The Second World War started that same year and the availability of this insulator enabled Britain to use airborne radar, giving them an enormous technical advantage and contributing significantly to their war effort (Olley, 2002). Therefore the rise of polymers was influenced by world events not merely chance …show more content…

In 1839 Edwin Simon discovered a new chemical named Styrol which he had isolated from a natural resin (EPSA, 2014). Twenty-five years later it was demonstrated that this hard material was actually a polymer, though the monomer was unstable. By the 1920s, new developments had stabilised it with the addition of small amounts of aromatic amines and phenols. This stabilisation led to the study of polymerisation throughout the 1920s. Thus it was not the discovery of the polymer which was important but the later development of it.
The polymerisation of polystyrene works on the same principle as that of polyethylene. The pi-bond between the carbons is broken by the free radical which forms a sigma-bond to the ethyl group. This allows the second carbon to break another pi-bond, and so on, to form a long chain. Polystyrene is similar to polyethylene except that it is bonded to a single benzene ring in place of a hydrogen atom, as shown in Figure 4. This benzene ring consists of six carbon atoms with three

Get Access