a) At 105°C, calculate y, and x, using Raoults law. b) If a mixture has a composition of x, = 0.40 and is at 85°C and 760 mm Hg pressure, will it boil? If not, at what temperature will it boil and what will be the composition of the vapor first coming off?

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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For the system benzene-toluene, do as follows using the data from the table below:
a) At 105°C, calculate y, and x, using Raoults law.
b) If a mixture has a composition of x4
what temperature will it boil and what will be the composition of the vapor first coming off?
0.40 and is at 85°C and 760 mm Hg pressure, will it boil? If not, at
Vapor Pressure
Mole Fraction Benzene
Temperature
Benzene
Toluene
at 101325 kPa
K
°C
kPa
mm Hg
kPa
тm Hg
353.3
80.1
101.32
760
1.000
1.000
358.2
85
116.9
877
46.0
345
0.780
0.900
363.2
90
135.5
1016
54.0
405
0.581
0.777
368.2
95
155.7
1168
63.3
475
0.411
0.632
373.2
100
179.2
1344
74.3
557
0.258
0.456
378.2
105
204.2
1532
86.0
645
0.130
0.261
383.8
110.6
240.0
1800
101.32
760
Transcribed Image Text:For the system benzene-toluene, do as follows using the data from the table below: a) At 105°C, calculate y, and x, using Raoults law. b) If a mixture has a composition of x4 what temperature will it boil and what will be the composition of the vapor first coming off? 0.40 and is at 85°C and 760 mm Hg pressure, will it boil? If not, at Vapor Pressure Mole Fraction Benzene Temperature Benzene Toluene at 101325 kPa K °C kPa mm Hg kPa тm Hg 353.3 80.1 101.32 760 1.000 1.000 358.2 85 116.9 877 46.0 345 0.780 0.900 363.2 90 135.5 1016 54.0 405 0.581 0.777 368.2 95 155.7 1168 63.3 475 0.411 0.632 373.2 100 179.2 1344 74.3 557 0.258 0.456 378.2 105 204.2 1532 86.0 645 0.130 0.261 383.8 110.6 240.0 1800 101.32 760
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