At −12.0 ∘C−12.0 ∘C, a common temperature for household freezers, what is the maximum mass of maltitol (C12H24O11) you can add to 2.50 kg2.50 kg of pure water and still have the solution freeze? Assume that maltitol is a molecular solid and does not ionize when it dissolves in water. Consult the table of ?fKf values.   Solvent Formula K f value* (°C/ m ) Normal freezing point ( °C)   K b value (°C/ m ) Normal boiling point ( °C)  water  H 2 O  1.86  0.00  0.512  100.00  benzene  C 6 H 6  5.12  5.49  2.53  80.1  cyclohexane  C 6 H 12  20.8  6.59  2.92  80.7  ethanol  C 2 H 6 O  1.99 –117.3  1.22  78.4  carbon  tetrachloride   CCl 4  29.8  –22.9  5.03  76.8  camphor   C 10 H 16 O  37.8  176

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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At −12.0 ∘C−12.0 ∘C, a common temperature for household freezers, what is the maximum mass of maltitol (C12H24O11) you can add to 2.50 kg2.50 kg of pure water and still have the solution freeze? Assume that maltitol is a molecular solid and does not ionize when it dissolves in water. Consult the table of ?fKf values.

 

Solvent

Formula

K f value*

(°C/ m )

Normal freezing

point ( °C)

  K b value

(°C/ m )

Normal boiling

point ( °C)

 water

 H 2 O

 1.86

 0.00

 0.512

 100.00

 benzene

 C 6 H 6

 5.12

 5.49

 2.53

 80.1

 cyclohexane

 C 6 H 12

 20.8

 6.59

 2.92

 80.7

 ethanol

 C 2 H 6 O

 1.99

–117.3

 1.22

 78.4

 carbon
 tetrachloride 

 CCl 4

 29.8

 –22.9

 5.03

 76.8

 camphor 

 C 10 H 16 O

 37.8

 176

 

 

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