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Considering a binary system 1,4-epoxybutane and water. They separate into two phases at 14.7 psi and 122°F. Using the two methods, a) Determine the equilibrium composition of each liquid phase. b) Find a graphical solution to part (a) by determining where the Gibbs energy of the system is at a minimum. Attach the plot. c) Using the criterion for inherent instability of a single liquid phase, determine the composition range over which the system is inherently unstable and will spontaneously separate into two phases. d) Following part (c), determine the ranges where the single liquid phase will not necessarily spontaneously separate into two phases. mol The system can be described by two - parameter Margules equation with A = 7400 and B = -1400 mol

Considering a binary system 1,4-epoxybutane and water. They separate into two phases at 14.7 psi and 122°F. Using the two methods, a) Determine the equilibrium composition of each liquid phase. b) Find a graphical solution to part (a) by determining where the Gibbs energy of the system is at a minimum. Attach the plot. c) Using the criterion for inherent instability of a single liquid phase, determine the composition range over which the system is inherently unstable and will spontaneously separate into two phases. d) Following part (c), determine the ranges where the single liquid phase will not necessarily spontaneously separate into two phases. mol The system can be described by two - parameter Margules equation with A = 7400 and B = -1400 mol

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Considering a binary system 1,4-epoxybutane and water. They separate into two phases at 14.7 psi and 122°F. Using the two methods, a) Determine the equilibrium composition of each liquid phase. b) Find a graphical solution to part (a) by determining where the Gibbs energy of the system is at a minimum. Attach the plot. c) Using the criterion for inherent instability of a single liquid phase, determine the composition range over which the system is inherently unstable and will spontaneously separate into two phases. d) Following part (c), determine the ranges where the single liquid phase will not necessarily spontaneously separate into two phases. The system can be described by two - parameter Margules equation with A = 7400 and B = -1400 mol mol
Transcribed Image Text:Considering a binary system 1,4-epoxybutane and water. They separate into two phases at 14.7 psi and 122°F. Using the two methods, a) Determine the equilibrium composition of each liquid phase. b) Find a graphical solution to part (a) by determining where the Gibbs energy of the system is at a minimum. Attach the plot. c) Using the criterion for inherent instability of a single liquid phase, determine the composition range over which the system is inherently unstable and will spontaneously separate into two phases. d) Following part (c), determine the ranges where the single liquid phase will not necessarily spontaneously separate into two phases. The system can be described by two - parameter Margules equation with A = 7400 and B = -1400 mol mol
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