For a liquid mixture of 10mol% ammonia in water, calculate the partial pressure of ammonia in the vapour phase at 10 °C, and the mole fraction of ammonia in the vapour phase, using data from Table 1. (linked).  Clearly state any assumptions.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Q6-3:

For a liquid mixture of 10mol% ammonia in water, calculate the partial pressure of ammonia in the vapour phase at 10 °C, and the mole fraction of ammonia in the vapour phase, using data from Table 1. (linked).  Clearly state any assumptions.

 

Ammonia – NH, (Refrigerant 717)
Superheat (T–T)
Saturation Values
50 K
100 K
h
T
Ps
Sg
h
S
['C] [bar] [m /kg]
[kJ/kg]
[kJ/kgK]
EkJ/kg] [kJ/kgK]
[kJ/kg] [kJ/kg K]
- 50
0.5454
0.7177
0.9322 1.216
1.196 0.9633
-0.194 6.159
-0.096 6.057
5.962
0.095 5.872
0.188 5.785
1585.9
1596.1
1606.3
1616.3
1626.3
6.948
6.839
6.736
6.639
6.547
0.4089
-45
-40
-35
- 30
2.625
2.005
1.552
-44.4 1373.3
-22.3 1381.6
1390.0
22.3 1397.9
44.7 1405.6
1479.8
1489.3
1498.6
1507.9
1517.0
6.592
6.486
6.387
6.293
6.203
-28 1.317
- 26 1.447
-24 1.588 0.7389
1.740
1.902
53.6 1408.5
62.6 1411.4
71.7 1414.3
80.8 1417.3
89.8 1420.0
1630.3
1634.2
1638.2
1642.2
1646.0
6.512
6.477
6.444
6.411
6.379
0.8809
0.8058
0.224 5.751
0.261 5.718
0.297 5.686
0.333 5.655
0.368 5.623
1520.7
6.169
6.135
1527.9 6.103
1531.4
1524.3
0.6783
0.6237
-22
6.071
- 20
1534.8
6.039
- 18
2.077
0.5743
0.5296
0.4890
0.4521
0.4185
98.8 1423.7
107.9 1425.3
117.0 1427.9
126.2 1430.5
135.4 1433.0
0.404 5.593
0.440 5.563
0.475 5.533
0.510 5.504
0.544 5.475
1538.2
1541.7
1545.1
1548.5
1551.7
6.008
5.978
5.948
5.919
5.891
1650.0
1653.8
1657.7
1661.5
1665.3
6.347
6.316
6.286
6.256
6.227
- 16
2.265
2.465
– 14
2.680
- 12
– 10
2.908
0.579 5.447 1554.9
0.613 5.419
0.647 5.392
0.681 5.365
0.715 5.340
3.153
0.3879
0.3599
0.3344
0.3110
0.2895
144.5 1435.3
153.6 1437.6
162.8 1439.9
172.0 1442.2
181.2 1444.4
5.863
5.836
5.808
5.782
5.756
1669.0
1672.8
1676.4
1680.1
1683.9
6.199
6.171
6.143
6.116
6.090
6
3.413
1558.2
1561.4
1564.6
1567.8
4
3.691
2
3.983
4.295
0.2699
0.2517
0.2351
0.2198
0.2056
190.4 1446.5
199.7 1448.5
209.1 1450.6
218.5 1452.5
227.8 1454.3
1570.9
1574.0
1577.0
1580.1
1583.1
5.731
5.706
5.682
5.658
5.634
1687.5
1691.2
1694.9
1698.4
1702.2
6.065
6.040
6.015
5.991
5.967
4.625
4
4.975
5.346
5.736
10
0.749 5.314
0.782 5.288
0.816 5.263
0.849 5.238
6.149
0.E1 5.213
Saturated Water and Steam
T
Ps
Sr
SE
['C]
[bar]
[m³/kg]
[kJ/kg]
[kJ/kg K]
0.01
0.006112
206.1
0*
2500.8
2500.8
9.155
9.155
0.006566
0.007054
0.007575
0.008129
2502.5
2504.3
2506.2
2508.1
0.015
0.031
0.046
0.061
9.128
9.102
9.076
9.050
1
192.6
179.9
168.2
157.3
4.2
8.4
12.6
16.8
2498.3
2495.9
2493.6
2491.3
9.113
9.071
9.030
8.989
3
4
5
6
7
8
0.008719
0.009346
0.01001
0.01072
0.01147
147.1
137.8
129.1
121.0
113.4
21.0
25.2
29.4
33.6
37.8
2488.9
2486.6
2484.3
2481.9
2479.6
2509.9
2511.8
2513.7
2515.5
2517.4
0.076
0.091
0.106
0.121
0.136
8.948
8.908
8.868
8.828
8.788
9.024
8.999
8.974
8.949
8.924
10
11
12
13
14
0.01227
0.01312
0.01401
0.01497
0.01597
106.4
99.90
93.83
88.17
82.89
42.0
46.2
50.4
54.6
58.8
2477.2
2474.9
2472.5
2470.2
2467.8
2519.2
2521.1
2522.9
2524.8
2526.6
0.151
0.166
0.180
0.195
0.210
8.749
8.710
8.671
8.633
8.594
8.900
8.876
8.851
8.828
8.804
Table 6.1. Thermodynamic data for ammonia, water and steam.
Transcribed Image Text:Ammonia – NH, (Refrigerant 717) Superheat (T–T) Saturation Values 50 K 100 K h T Ps Sg h S ['C] [bar] [m /kg] [kJ/kg] [kJ/kgK] EkJ/kg] [kJ/kgK] [kJ/kg] [kJ/kg K] - 50 0.5454 0.7177 0.9322 1.216 1.196 0.9633 -0.194 6.159 -0.096 6.057 5.962 0.095 5.872 0.188 5.785 1585.9 1596.1 1606.3 1616.3 1626.3 6.948 6.839 6.736 6.639 6.547 0.4089 -45 -40 -35 - 30 2.625 2.005 1.552 -44.4 1373.3 -22.3 1381.6 1390.0 22.3 1397.9 44.7 1405.6 1479.8 1489.3 1498.6 1507.9 1517.0 6.592 6.486 6.387 6.293 6.203 -28 1.317 - 26 1.447 -24 1.588 0.7389 1.740 1.902 53.6 1408.5 62.6 1411.4 71.7 1414.3 80.8 1417.3 89.8 1420.0 1630.3 1634.2 1638.2 1642.2 1646.0 6.512 6.477 6.444 6.411 6.379 0.8809 0.8058 0.224 5.751 0.261 5.718 0.297 5.686 0.333 5.655 0.368 5.623 1520.7 6.169 6.135 1527.9 6.103 1531.4 1524.3 0.6783 0.6237 -22 6.071 - 20 1534.8 6.039 - 18 2.077 0.5743 0.5296 0.4890 0.4521 0.4185 98.8 1423.7 107.9 1425.3 117.0 1427.9 126.2 1430.5 135.4 1433.0 0.404 5.593 0.440 5.563 0.475 5.533 0.510 5.504 0.544 5.475 1538.2 1541.7 1545.1 1548.5 1551.7 6.008 5.978 5.948 5.919 5.891 1650.0 1653.8 1657.7 1661.5 1665.3 6.347 6.316 6.286 6.256 6.227 - 16 2.265 2.465 – 14 2.680 - 12 – 10 2.908 0.579 5.447 1554.9 0.613 5.419 0.647 5.392 0.681 5.365 0.715 5.340 3.153 0.3879 0.3599 0.3344 0.3110 0.2895 144.5 1435.3 153.6 1437.6 162.8 1439.9 172.0 1442.2 181.2 1444.4 5.863 5.836 5.808 5.782 5.756 1669.0 1672.8 1676.4 1680.1 1683.9 6.199 6.171 6.143 6.116 6.090 6 3.413 1558.2 1561.4 1564.6 1567.8 4 3.691 2 3.983 4.295 0.2699 0.2517 0.2351 0.2198 0.2056 190.4 1446.5 199.7 1448.5 209.1 1450.6 218.5 1452.5 227.8 1454.3 1570.9 1574.0 1577.0 1580.1 1583.1 5.731 5.706 5.682 5.658 5.634 1687.5 1691.2 1694.9 1698.4 1702.2 6.065 6.040 6.015 5.991 5.967 4.625 4 4.975 5.346 5.736 10 0.749 5.314 0.782 5.288 0.816 5.263 0.849 5.238 6.149 0.E1 5.213 Saturated Water and Steam T Ps Sr SE ['C] [bar] [m³/kg] [kJ/kg] [kJ/kg K] 0.01 0.006112 206.1 0* 2500.8 2500.8 9.155 9.155 0.006566 0.007054 0.007575 0.008129 2502.5 2504.3 2506.2 2508.1 0.015 0.031 0.046 0.061 9.128 9.102 9.076 9.050 1 192.6 179.9 168.2 157.3 4.2 8.4 12.6 16.8 2498.3 2495.9 2493.6 2491.3 9.113 9.071 9.030 8.989 3 4 5 6 7 8 0.008719 0.009346 0.01001 0.01072 0.01147 147.1 137.8 129.1 121.0 113.4 21.0 25.2 29.4 33.6 37.8 2488.9 2486.6 2484.3 2481.9 2479.6 2509.9 2511.8 2513.7 2515.5 2517.4 0.076 0.091 0.106 0.121 0.136 8.948 8.908 8.868 8.828 8.788 9.024 8.999 8.974 8.949 8.924 10 11 12 13 14 0.01227 0.01312 0.01401 0.01497 0.01597 106.4 99.90 93.83 88.17 82.89 42.0 46.2 50.4 54.6 58.8 2477.2 2474.9 2472.5 2470.2 2467.8 2519.2 2521.1 2522.9 2524.8 2526.6 0.151 0.166 0.180 0.195 0.210 8.749 8.710 8.671 8.633 8.594 8.900 8.876 8.851 8.828 8.804 Table 6.1. Thermodynamic data for ammonia, water and steam.
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