Problem 1: In thermodynamics, any region that occupies a volume and has a boundary is called a system. The volume outside the boundary is called the surroundings of the system. The sum of the system and its surroundings is called the universe, which is an isolated system. In astrophysics, on the other hand, universe is all of space and time (space-time) and its contents including planets, moons, minor planets, stars, galaxies, and all known and unknown matters and energy. Today, we know that the universe is expanding at an increasing rate, which is one of the most fascinating scientific discoveries. With today’s advanced technology, such as Hubble Space Telescope, we can measure this expansion rate very accurately. Now, assume that our universe is an isolated, single-phase system: A) How do you explain this expansion by the 2nd Law of Thermodynamics? What is the entropy balance of our universe? B) When do you think this phenomenon will stop? And what will be the entropy balance then? C) What will be the temperature and pressure profiles across the universe when the expansion stops?

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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Problem 1: In thermodynamics, any region that occupies a volume and has a boundary is called 
a system. The volume outside the boundary is called the surroundings of the system. The sum of 
the system and its surroundings is called the universe, which is an isolated system. 
In astrophysics, on the other hand, universe is all of space and time (space-time) and its contents 
including planets, moons, minor planets, stars, galaxies, and all known and unknown matters and 
energy. Today, we know that the universe is expanding at an increasing rate, which is one of the 
most fascinating scientific discoveries. With today’s advanced technology, such as Hubble Space 
Telescope, we can measure this expansion rate very accurately. 
Now, assume that our universe is an isolated, single-phase system: 
A) How do you explain this expansion by the 2nd Law of Thermodynamics? What is the entropy 
balance of our universe? 
B) When do you think this phenomenon will stop? And what will be the entropy balance then? 
C) What will be the temperature and pressure profiles across the universe when the expansion 
stops? 
D) Once the expansion stops, would you able to generate electric energy from the sun using a 
solar system? Explain why. 

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