Question A3 Cesium hydride, CsH, has the cesium chloride structure with unit cell parameter a = 3.82 Å. a) Calculate the Coulomb (ionic) energy of CsH, assuming that the ions have their formal charges Cs and H. Give your answer in kJ mol-1. b) A neutron diffraction pattern was measured from a powder sample of this material. The neutron scattering length of Cs is 5.42 fm and of H is -3.74 fm. Calculate the structure factor and multiplicity of (i) the (200) diffraction peak; and (ii) the (210) diffraction peak. Hence (iii) estimate the ratio of the intensity of the (200) to the (210) peak in the diffraction pattern.

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Question A3
Cesium hydride, CsH, has the cesium chloride structure with unit cell parameter a = 3.82 Å.
a) Calculate the Coulomb (ionic) energy of CsH, assuming that the ions have their formal
charges Cs and H. Give your answer in kJ mol-1.
b) A neutron diffraction pattern was measured from a powder sample of this material. The
neutron scattering length of Cs is 5.42 fm and of H is -3.74 fm. Calculate the structure factor
and multiplicity of
(i) the (200) diffraction peak; and
(ii) the (210) diffraction peak.
Hence
(iii) estimate the ratio of the intensity of the (200) to the (210) peak in the diffraction pattern.
Transcribed Image Text:Question A3 Cesium hydride, CsH, has the cesium chloride structure with unit cell parameter a = 3.82 Å. a) Calculate the Coulomb (ionic) energy of CsH, assuming that the ions have their formal charges Cs and H. Give your answer in kJ mol-1. b) A neutron diffraction pattern was measured from a powder sample of this material. The neutron scattering length of Cs is 5.42 fm and of H is -3.74 fm. Calculate the structure factor and multiplicity of (i) the (200) diffraction peak; and (ii) the (210) diffraction peak. Hence (iii) estimate the ratio of the intensity of the (200) to the (210) peak in the diffraction pattern.
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