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rted by 1.0 mol of hydrogen at 0°C in a vessel with volume of 5.0 dm^3 using: a. the virial equation of state up to 2nd virial coefficient (use constant

rted by 1.0 mol of hydrogen at 0°C in a vessel with volume of 5.0 dm^3 using: a. the virial equation of state up to 2nd virial coefficient (use constant

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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calculate the pressure exerted by 1.0 mol of hydrogen at 0°C in a vessel with volume of 5.0 dm^3 using: a. the virial equation of state up to 2nd virial coefficient (use constant from table 1c.1, p. 868(see picture))
Table 1C.1 Second virial coefficients, B/(cm mol") 100 K 273 K 373 K 600 K Air -167.3 -13.5 3.4 19.0 Ar -187.0 -21.7 -4.2 11.9 CH, -53.6 -21.2 8.1 CO, -142 -72.2 -12.4 H, -2.0 13.7 15.6 Не 11.4 12.0 11.3 10.4 Kr -62.9 -28.7 1.7 N2 -160.0 -10.5 6.2 21.7 Ne -6.0 10.4 12.3 13.8 O, -197.5 -22.0 -3.7 12.9 Хе -153.7 -81.7 -19.6 Data: AIP, JL. The values relate to the expansion in eqn 1C.3b of Topic 1C; convert to eqn 1C.3a by using B' = B/RT. For Ar at 273K, C= 1200 cm mol.
Transcribed Image Text:Table 1C.1 Second virial coefficients, B/(cm mol") 100 K 273 K 373 K 600 K Air -167.3 -13.5 3.4 19.0 Ar -187.0 -21.7 -4.2 11.9 CH, -53.6 -21.2 8.1 CO, -142 -72.2 -12.4 H, -2.0 13.7 15.6 Не 11.4 12.0 11.3 10.4 Kr -62.9 -28.7 1.7 N2 -160.0 -10.5 6.2 21.7 Ne -6.0 10.4 12.3 13.8 O, -197.5 -22.0 -3.7 12.9 Хе -153.7 -81.7 -19.6 Data: AIP, JL. The values relate to the expansion in eqn 1C.3b of Topic 1C; convert to eqn 1C.3a by using B' = B/RT. For Ar at 273K, C= 1200 cm mol.
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