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Show that the initial rate law predicted by the reaction mechanism 6-12a- with the first step rate-limiting, is rate = 2k,[Cl]. Assume that the Cl. %3D

Show that the initial rate law predicted by the reaction mechanism 6-12a- with the first step rate-limiting, is rate = 2k,[Cl]. Assume that the Cl. %3D

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Show that the initial rate law predicted by the reaction mechanism 6-12a-c, with the first step rate-limiting, is rate = 2k,[Cl,]. Assume that the Cl - produced in step (3) can be neglected initially.
Transcribed Image Text:Show that the initial rate law predicted by the reaction mechanism 6-12a-c, with the first step rate-limiting, is rate = 2k,[Cl,]. Assume that the Cl - produced in step (3) can be neglected initially.
Cl, से 2C1 (6-12a) CI- + CO p CIĊO (6-12b) + Cle CICO + Cl· (6-12c)
Transcribed Image Text:Cl, से 2C1 (6-12a) CI- + CO p CIĊO (6-12b) + Cle CICO + Cl· (6-12c)
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