The addition of 5 grams of a compound to 750 g of CCl4 lowered the freezing point of the solvent by 10.5K. Calculate the molar mass of the compound.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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 The addition of 5 grams of a compound to 750 g of CCl4 lowered the freezing point of the solvent by 10.5K. Calculate the molar mass of the compound.

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Table 2.3 Standard enthalpies of fusion and vaporization at the transition temperature, Atrg H®/(kJ mol")
T;IK
Fusion
T/K
Vaporization
T;/K
Fusion
T,/K
Vaporization
Elements
CO,
217.0
8.33
194.6
25.23 s
Ag
1234
11.30
2436
250.6
CS,
161.2
4.39
319.4
26.74
Ar
83.81
1.188
87.29
6.506
H,O
273.15
6.008
373.15
40.656
Br2
265.9
10.57
332.4
29.45
44.016 at 298K
Cl2
H,S
172.1
6.41
239.1
20.41
187.6
2.377
212.8
18.67
F,
53.6
0.26
85.0
3.16
H,SO,
283.5
2.56
H,
13.96
0.117
20.38
0.916
NH3
195.4
5.652
239.7
23.35
Не
3.5
0.021
4.22
0.084
Organic compounds
Hg
234.3
2.292
629.7
59.30
CH,
90.68
0.941
111.7
8.18
386.8
15.52
458.4
41.80
250.3
2.5
350
30.0
N2
63.15
0.719
77.35
5.586
CH,
89.85
2.86
184.6
14.7
Na
371.0
2.601
1156
98.01
CH6
278.61
10.59
353.2
30.8
O2
6.820
54.36
0.444
90.18
CH14
178
13.08
342.1
28.85
Хе
161
2.30
165
12.6
354
18.80
490.9
51.51
K
336.4
2.35
1031
80.23
CH,OH
175.2
3.16
337.2
35.27
Inorganic compounds
37.99 at 298 K
CCI,
250.3
2.47
30.00
CH,OH
158.7
4.60
352
43.5
349.9
Data: AIP; s denotes sublimation.
Transcribed Image Text:Table 2.3 Standard enthalpies of fusion and vaporization at the transition temperature, Atrg H®/(kJ mol") T;IK Fusion T/K Vaporization T;/K Fusion T,/K Vaporization Elements CO, 217.0 8.33 194.6 25.23 s Ag 1234 11.30 2436 250.6 CS, 161.2 4.39 319.4 26.74 Ar 83.81 1.188 87.29 6.506 H,O 273.15 6.008 373.15 40.656 Br2 265.9 10.57 332.4 29.45 44.016 at 298K Cl2 H,S 172.1 6.41 239.1 20.41 187.6 2.377 212.8 18.67 F, 53.6 0.26 85.0 3.16 H,SO, 283.5 2.56 H, 13.96 0.117 20.38 0.916 NH3 195.4 5.652 239.7 23.35 Не 3.5 0.021 4.22 0.084 Organic compounds Hg 234.3 2.292 629.7 59.30 CH, 90.68 0.941 111.7 8.18 386.8 15.52 458.4 41.80 250.3 2.5 350 30.0 N2 63.15 0.719 77.35 5.586 CH, 89.85 2.86 184.6 14.7 Na 371.0 2.601 1156 98.01 CH6 278.61 10.59 353.2 30.8 O2 6.820 54.36 0.444 90.18 CH14 178 13.08 342.1 28.85 Хе 161 2.30 165 12.6 354 18.80 490.9 51.51 K 336.4 2.35 1031 80.23 CH,OH 175.2 3.16 337.2 35.27 Inorganic compounds 37.99 at 298 K CCI, 250.3 2.47 30.00 CH,OH 158.7 4.60 352 43.5 349.9 Data: AIP; s denotes sublimation.
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