The formation of orthonitroaniline is from the reaction of orthonitrochlorobenzene (ONCB) and aqueous ammonia. C6H4ClNO2 + 2NH3 → O2NC6H4NH2 + NH4Cl This liquid-phase reaction is first order in both ONCB and ammonia with k = 0.0017 m3/kmol•min at 188 oC with E = 11273 cal/mol. The initial entering concentration of ONCB and ammonia are 1.8 kmol/m3 and 6.6 kmol/m3, respectively.  Gas constant: R = 1.987 cal/(K∙mol).   (a) Write the rate law for the rate of disappearance of ONCB in terms of molar concentration. (b) Set up a stoichiometric table for a flow system with respect to the flow rate. (c) Write –rA solely as a function of conversion.

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The formation of orthonitroaniline is from the reaction of orthonitrochlorobenzene (ONCB) and aqueous ammonia.

C6H4ClNO2 + 2NH3 → O2NC6H4NH2 + NH4Cl

This liquid-phase reaction is first order in both ONCB and ammonia with k = 0.0017 m3/kmol•min at 188 oC with E = 11273 cal/mol. The initial entering concentration of ONCB and ammonia are 1.8 kmol/m3 and 6.6 kmol/m3, respectively.  Gas constant: R = 1.987 cal/(K∙mol).  

(a) Write the rate law for the rate of disappearance of ONCB in terms of molar concentration.

(b) Set up a stoichiometric table for a flow system with respect to the flow rate.

(c) Write –rA solely as a function of conversion.

(d) What is the initial rate of reaction (X = 0) at 188 oC?

(e) What is the initial rate of reaction (X = 0) at 25 oC?

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