The pressures deep within the Earth are much greaterthan those on the surface, and to make use of thermochemical data in geochemical assessments you need to take thedifferences into account. (a) Given that the enthalpy of combustion of graphite is -393.5 kJ mol-' and that of diamondis -395.41 kJ mol-', calculate the standard enthalpy of theC(s, graphite) ~ C(s, diamond) transition. (b) The densitiesof graphite and diamond are 2.250 g cm3 and 3.510 g cm-3,respectively. Calculate the internal energy of the transitionwhen the sample is under a pressure of 150 kbar.

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The pressures deep within the Earth are much greater
than those on the surface, and to make use of thermochemical data in geochemical assessments you need to take the
differences into account. (a) Given that the enthalpy of combustion of graphite is -393.5 kJ mol-' and that of diamond
is -395.41 kJ mol-', calculate the standard enthalpy of the
C(s, graphite) ~ C(s, diamond) transition. (b) The densities
of graphite and diamond are 2.250 g cm3 and 3.510 g cm-3,
respectively. Calculate the internal energy of the transition
when the sample is under a pressure of 150 kbar.

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