tion of NO2 is 0.050M, dete

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
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d) The reaction
2NO, (g)
2NO (g) + 02 (9)
has the rate constantk = 0.63 M's1.
i. Determine the order of the reaction in NO2.
ii. If the initial concentration of NO2 is 0.050M, determine the concentration of this
reactant after 0.50 hours.
ii.
The NO in the above reaction is used to produce nitrosyl chloride (NOCI) as shown
below:
2NO (g) + Cl, (g)
2NOCI (g)
The following data was then obtained.
(under conditions of constant [Cl,])
Time
Determine if the following mechanism is consistent with the data. Explain your answer.
NO (g) + Cl, (g)
NOCI, (g)
(fast)
NOCI, (g) + NO (g)
2NOCI (g)
(slow)
1/[NO]
Transcribed Image Text:d) The reaction 2NO, (g) 2NO (g) + 02 (9) has the rate constantk = 0.63 M's1. i. Determine the order of the reaction in NO2. ii. If the initial concentration of NO2 is 0.050M, determine the concentration of this reactant after 0.50 hours. ii. The NO in the above reaction is used to produce nitrosyl chloride (NOCI) as shown below: 2NO (g) + Cl, (g) 2NOCI (g) The following data was then obtained. (under conditions of constant [Cl,]) Time Determine if the following mechanism is consistent with the data. Explain your answer. NO (g) + Cl, (g) NOCI, (g) (fast) NOCI, (g) + NO (g) 2NOCI (g) (slow) 1/[NO]
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