Use the van der waals constant for CH4 in table 1.3 to calculate the intial slopes of the plot of the compressibility factor Z versus P at 300 and 600 K.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Use the van der waals constant for CH4 in table 1.3 to calculate the intial slopes of the plot of the compressibility factor Z versus P at 300 and 600 K.

and b are constants characteristic 8l
Table 1.3
van der Waals Constants and Boiling Points of Some Substances
a/atm L2 mol-2
b/L mol-1
Boiling point/K
Substance
Не
0.0341
0.0237
4.2
Ne
0.214
0.0174
27.2
Ar
1.34
0.0322
87.3
H2
0.240
0.0264
20.3
N2
1.35
0.0386
77.4
O2
1.34
0.0312
90.2
CO
1.45
0.0395
83.2
CO2
3.60
0.0427
195.2
CH4
2.26
0.0430
109.2
C,H,
5.47
0.0651
184.5
H,0
5.54
0.0305
373.15
NH3
4.25
0.0379
239.8
Transcribed Image Text:and b are constants characteristic 8l Table 1.3 van der Waals Constants and Boiling Points of Some Substances a/atm L2 mol-2 b/L mol-1 Boiling point/K Substance Не 0.0341 0.0237 4.2 Ne 0.214 0.0174 27.2 Ar 1.34 0.0322 87.3 H2 0.240 0.0264 20.3 N2 1.35 0.0386 77.4 O2 1.34 0.0312 90.2 CO 1.45 0.0395 83.2 CO2 3.60 0.0427 195.2 CH4 2.26 0.0430 109.2 C,H, 5.47 0.0651 184.5 H,0 5.54 0.0305 373.15 NH3 4.25 0.0379 239.8
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