Using the equilibrium data shown below for benzene-toluene system at 1 atm with relative volatility of 2.5: a. Construct an enthalpy-composition (H-x-y) diagram for the mixture. b. From the plot, calculate the energy required for 50% vaporization of a 30 mol% liquid solution of benzene in toluene at saturation temperature. c. If the vapor in equilibrium with the liquid phase is condensed, what is the heat load on the condenser in kJ/kg of the solution if the condensate is saturated?

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Using the equilibrium data shown below for benzene-toluene system at 1 atm with relative volatility of 2.5:

a. Construct an enthalpy-composition (H-x-y) diagram for the mixture.
b. From the plot, calculate the energy required for 50% vaporization of a 30 mol% liquid solution of benzene in toluene at saturation temperature.
c. If the vapor in equilibrium with the liquid phase is condensed, what is the heat load on the condenser in kJ/kg of the solution if the condensate is saturated?

Molar composition
Enthalpy (kJ/kg)
Xa
Ya
hy
1
116.2
511.1
0.775
0.899
124.7
515.4
0.579
0.776
133.6
519.7
0.408
0.63
142.5
523.8
0.259
0.459
151.5
527.7
0.128
0.259
160.5
531.5
170.4
535.5
Transcribed Image Text:Molar composition Enthalpy (kJ/kg) Xa Ya hy 1 116.2 511.1 0.775 0.899 124.7 515.4 0.579 0.776 133.6 519.7 0.408 0.63 142.5 523.8 0.259 0.459 151.5 527.7 0.128 0.259 160.5 531.5 170.4 535.5
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