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Essay on Computerized Data Acquisition of a Second Order Reaction

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Computerized Data Acquisition of a Second Order Reaction Abstract Introduction The rates at which reactions occur depend on the composition and the temperature of the reaction mixture. Usually the rate of reaction is found to be proportional to the concentrations of the reactants raised to a power.1 There are many reactions that have a rate law in the form of: (1) v = k[A]a[B]b According to reference1 the power to which the concentration of a species (product or reactant) is raised in a rate law of this nature is the order of the reaction with respect to that species. In equation (1) first order with respect to [A] and first order with respect to [B]; however, the overall reaction is the sum of the individual orders. Thus …show more content…

The Erlenmeyer flask was swirled for 2-3 seconds before pouring the reacting mixture into a 1-cm cuvette. The cuvette was conditioned with the reacting solution 4 times before being placed into the sample holder of the spectrophotometer. An absorbance reading was taken at 30 seconds and every 30 seconds thereafter for a total of 6 minutes. The same process was implemented with the Cary 50 Bio except that each sample was analyzed by the computer for 7 minutes and 53 seconds. Data/Results 0.025 M NaNO3 0.05 M NaNO3 Time (sec) Asb [K3Fe(CN)6] [C6H8O6] Asb [K3Fe(CN)6] [C6H8O6] 30 0.622 0.0006146 0.0003573 0.653 0.00065 0.0003726 60 0.617 0.0006097 0.0003548 0.640 0.00063 0.0003662 90 0.606 0.0005988 0.0003494 0.628 0.00062 0.0003603 120 0.600 0.0005929 0.0003464 0.619 0.00061 0.0003558 150 0.593 0.0005860 0.0003430 0.609 0.00060 0.0003509 180 0.584 0.0005771 0.0003385 0.600 0.00059 0.0003464 210 0.578 0.0005711 0.0003356 0.591 0.00058 0.0003420 240 0.571 0.0005642 0.0003321 0.583 0.00058 0.0003380 270 0.564 0.0005573 0.0003287 0.575 0.00057 0.0003341 300 0.559 0.0005524 0.0003262 0.567 0.00056 0.0003301 330 0.552 0.0005455 0.0003227 0.560 0.00055 0.0003267 360 0.546 0.0005395 0.0003198 0.553 0.00055 0.0003232 0.01 M NaNO3 0.2 M NaNO3 Time (sec) Asb [K3Fe(CN)6] [C6H8O6] Asb

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