Specific Heat of Solids
I. Objective
The objective of the study is to explain, measure and better understand the specific heat of copper and lead using the method of mixtures.
II. Theory
Heat is a form of energy it is either expressed in joules, calories, or kilo-calories According to the law formulated by the French chemists Pierre Louis Dulong and Alexis Thérèse Petit, the specific heat of solids which is characterized as the amount of heat required to raise the temperature of one gram of a substance to one degree Celsius specimens are inversely proportional to their atomic weights; that is, the specific heat multiplied by the atomic weight is approximately a constant quantity for all the solid elements.
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Once again, we assume the system to be thermally insulated from the surroundings, and the heat capacity of the thermometer, which records the temperature, can be neglected. Let the final temperature of the mixture be T3. Energy conservation gives:
Qlost(specimen) = Qgained(Water) + Qgained(Calorimeter)
which yields the unknown specific heat c1 of the specimen as c1 = (m2c2+m3c3) (T3 - T2) m1(T1 ? T3)
We assume that the mixing can be done without loss of heat by the hot specimen to the surroundings.
We will consider a specimen heated to a high temperature is dropped into water contained in a calorimeter cup at a lower temperature. If this system is thermally insulated from the surroundings, the specific heat of the specimen can be determined by equating the heat lost by the metal to the heat gained by both the calorimeter cup and the water contained in it. (http://www.physics1.howard.edu/MSIP/GenLab1/GL1-10.pdf )
III. Diagram/Materials
IV. Procedure
The initial masses of boiler dipper, copper, lead, dipper and shots, inner vessel with water, and water are measured and recorded. The specimens (copper/lead) are heated and the initial temperatures are recorded after which, it is dropped in the calorimeter containing cold water. The temperature rise of the water in the calorimeter is observed and recorded. From the data gathered, the specific
In order to measure the heats of reactions, add the reactants into the calorimeter and measure the difference between the initial and final temperature. The temperature difference helps us calculate the heat released or absorbed by the reaction. The equation for calorimetry is q=mc(ΔT). ΔT is the temperature change, m is the mass, c is the specific heat capacity of the solution, and q is the heat transfer. Given that the experiment is operated under constant pressure in the lab, the temperature change is due to the enthalpy of the reaction, therefore the heat of the reaction can be calculated.
For q, you found how much heat was gained by the water so you know that same amount of heat was lost by the metal. Therefore, qmetal = -qwater. The mass of the sample was recorded from the baggie. The temperature change
When the volumes of NaOH and CH3COOH were equal, the temperature increased by 5 degrees celsius. When we performed a second trial and added 15 mL of NaOH and 5 mL of CH3COOH, the temperature only showed an increase
Finally, we measured the mass of the remaining copper in the test tube. This lead to the discovery that the mass of the copper in relation to our original 1.08 grams of copper oxide was 0.96 grams. From this data, we could find that the measurement of oxygen in our amount of copper oxide was 0.12 grams. With these significant weights, we were then able to convert those results to the amount of moles each element had in contribution to our total quantity of copper oxide. Specifically, we found that there was 0.015 moles of copper in our copper oxide, and 0.0075 moles of oxygen. So, that made the calculated ratio between moles of copper and moles of oxygen to be 2.0, or a 2:1 ratio of copper to oxygen. Thus, the formula of the red copper oxide can be expressed as . The lab worked the way it did primarily because of the chemical characteristics of copper oxide. Since the oxygen could separate from the copper when presented with a heat source, it allowed for the amount of each element in our quantity of copper oxide to be measured and then calculated into a ratio, which determined the formula for the
We can assume that the specific heat capacity of water is 4.18 J / (g × °C) and the density of water is 1.00 g/mL.
3. When heat flows from a warm object in contact with a cool object, do both objects undergo the same amount of temperature change?
16. Use the equation: q = m(SH)ΔT to solve for the amount of heat gained by the water from metal. You have
In this experiment, we investigate the change in temperature caused by adding a chemical substance into the water and dissolving it. The results recorded in the table below show that our hypothesis is correct.
The lab used methods of calorimetry in order to measure the temperature change of reactions and calculate the changes in
Thermal energy is the energy a substance or system has related to its temperature. This means the energy of moving or vibrating molecules. Atoms and molecules are always in motion. Generally the motion of thermal energy cannot be seen, but instead the effects it has on the substance can be seen or felt. Thermal energy can have several different uses. It can be used to heat homes, cook food, and generate electricity.
We will be using 6 different fuels to heat up 100ml of water, and find out the changes of the temperature. We will measure the temperatures of the water before and after the experiment. We will burn heat the water for exactly 2 minutes, and check the changes in temperature. The change in temperature will allow us to work out the energy given off the fuel by using this formula:
Heat is a form of energy that is transferred between two substances at different temperatures. The flow of the energy is from the object of higher temperature to the object of lower temperature. The heat is measured in units of energy, usually calories or joules. Temperature on the other hand, is how cold or hot an object is. The temperature is the average kinetic energy per molecule of a substance. This is measured in degrees on the Celsius or Fahrenheit or in Kelvins.
The temperature-time plot gotten by applying a lumped-parameter analysis (Equation 6) to the Aluminum cylinder was compared to the plot obtained from the thermocouple located closest to center of the cylinder. This thermocouple is chosen for comparison because it is located farthest from the heating source and will have a temperature history that differs most from an ideal lumped system. With this thermocouple, we should therefore obtain the maximum error associated with applying a
Overall, the experiment succeeded that the metals show the theoretical properties. Differences existed in the mathematical calculation of the actual length. These differences, however, it can be accounted for by experimental error; more over there are uncertainty on purity of the
Introduction: Every chemical change is accompanied by a change in energy usually in the form of heat. If heat is evolved, the reaction is exothermic, and if heat is absorbed, the reaction is endothermic. The energy change of a reaction that occurs at constant pressure is called the heat of reaction or the enthalpy of reaction (ΔHr). This quantity of heat is measured experimentally by allowing the reaction to occur in a calorimeter. In this experiment you will determine the heat of neutralization when an acid and a base react to form 1 mole of water. In a perfect calorimeter, heat is exchanged only between the reaction and the calorimeters water. Technically, some heat may may be absorbed the calorimeter. All calorimeters exchange some heat with its environment. This amount of heat is called the calorimeters heat capacity (the amount of of heat required to raise its temperature 1∘Celsius). We are going to “pretend” that our calorimeter is the perfect calorimeter.