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Acid Rain Essay

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Rain is crucial in creating a balanced ecosystem. It restores moisture in the air, progresses the water cycle, nurtures thousands of plant and animal life, and even dampens the soil to help earthworms aerate the lithosphere. However, a combination of rain and gaseous pollutants from natural and anthropogenic sources threatens to alter the geochemistry of the Earth today. In particular, acid rain, a mixture of wet and dry deposition containing harmful gases, can create complex biogeochemical changes in soil that may adversely affect all terrestrial living systems, including the Lumbricus terrestris- otherwise known as the common earthworm.
There are three ways of interpreting the acidity of soil: acidic (pH<7), basic (pH>7), and neutral (pH=7). Acidity is measured by the concentration of hydrogen ions ([H+]) which can be converted to pH using the equation pH= –log[H+]. According to the United States Environmental Protection Agency (EPA), normal rainwater has a pH of approximately 5.6 which is slightly acidic due to the presence of dissolved carbon dioxide from the air reacting with water to form weak carbonic acid (pKa1 = 6.367, pKa2 = 10.32), shown in the equations below (1).
CO2(g) + H2O(l) H2CO3(aq) (Equation 1)
H2CO3(aq) H+(aq) + HCO3-(aq) (Equation 2)
The acidity of normal rainwater comes from the natural presence of three substances: carbon dioxide, nitrogen oxides, and sulfur dioxide (CO2, NOx, and SO2) found in the troposphere . In terms of ppm, carbon

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