Multiple scientific concepts were exemplified in this experiment and one particular goal of this lab was to learn more about the Beer-Lambert Law which establishes a linear relationship between the concentration of a solution and the amount of light that the solution absorbs. Moreover, another objective of this experiment was to gain an understanding about the mechanical components of a spectrophotometer and to successfully use the device to measure absorbance or transmittance values. Lastly, another goal of this lab was to understand the concept of calibration curves and the process of interpolating data. Essentially, this lab utilized all of the processes mentioned above to determine the percentage of copper in a penny. Standard …show more content…
Introduction
Scientific Background Concepts The determination of the amount of copper in a penny involves multiple scientific concepts that are extremely important. First, the experiment involves a redox reaction of Copper and Zinc. Copper and zinc are both components of a penny and the oxidation reaction utilizes nitric acid, a very strong oxidizing agent, in order to oxidize both copper and zinc. The reaction generates a highly toxic, brown gas which is nitrogen dioxide (NO2), but more importantly, it results in the complex ions of copper and zinc. The complex ion generated of copper is Cu(H2O)42+ and has a dark blue hue while the complex ion generated of zinc is Zn(H2O)42+ and does not have a distinctive color. Essentially, a complex ion is formed by having a central metal ion that has formed covalent bonds with multiple ligands, which are simply anions. Furthermore, the Beer-Lambert Law establishes a relationship between light absorption and solution concentration by claiming that the concentration of a certain solution is directly proportionate to the total amount of light energy that the compound present in the solution can absorb (The Beer-Lambert). A spectrophotometer can be utilized to measure how much light energy of a certain chosen wavelength is absorbed by a particular sample.
Objectives
There are multiple goals that are to be achieved by
Due to this fact, the concentration of copper in the solution is able to be calculated by using light absorbance. Since zinc doesn’t absorb any light, we are able to deduce that the greater the absorbance, the greater the concentration of copper.
After this, the solution was poured into a volumetric flask just about to the 1dm3 line and then it was left there to cool to the same temperature as the room before filling precisely to the 1dm3 line with distilled water. The molar mass of CuSO4.5H20 was 249.5 so that means 249.5g of copper sulphate was needed to dissolve, in order to make a standard solution, into 1dm3of distilled water. Following this, a linear dilution of the CuSO4.5H2O was made in order to be used to make a calibration curve after using the colorimeter to write down the absorbance of each sample. A linear dilution is diluted with distilled water in order for it to make the concentration weaker and weaker. For this investigation, the dilutions made ranged from 0.01 to 0.1 M/l . It was essential to only make up 10cm3
The mole is a convenient unit for analyzing chemical reactions. Avogadro’s number is equal to the mole. The mass of a mole of any compound or element is the mass in grams that corresponds to the molecular formula, also known as the atomic mass. In this experiment, you will observe the reaction of iron nails with a solution of copper (II) chloride and determine the number of moles involved in the reaction. You will determine the number of moles of copper produced in the reaction of iron and copper (II) chloride, determine the number of moles of iron used up in the reaction of iron and copper (II) chloride, determine the ratio of moles of iron to moles of copper, and determine the number of atoms and formula units involved in
Obtain a 50 mL beaker for the experiment. In the first part of the experiment, you dissolve the zinc core of a penny and leave the copper covering intact by putting four notches in
One of the most important skills to have in the chemistry lab is the understanding of how chemicals will react. Knowing for example, how a chemical will react with a metal, is an excellent way of determining the amount of a particular metal in a deposit. This knowledge was used in this lab to determine the amount of copper in an unknown sample mixture. It is also known that the determination of the percent concentration of a certain solution, will directly effect the percent transmission and absorption of a solution, dependent upon its dilution. By first testing known concentrations of a solution, and plotting this information graphically, a line is formed
The purpose of this experiment was to find, compare, and contrast the mass, volume, and densities of copper and zinc pennies. Information about the pennies was acquired before the start of the lab. The pre-lab research stated that any pennies that were minted before 1982 are composed of pure copper, while any pennies after 1982 are made out of zinc. The densities of copper -- 8.96 grams per centimeters cubed -- and zinc -- 7.13 grams per centimeters cubed -- were also information that was acquired before starting the experiment. With knowing the density of the two metals, this hypothesis was formed: If the mass and volume of pennies made out of zinc and copper are both measured, then the copper pennies will have a greater mass, because copper has a greater density than zinc. This hypothesis was formed because density equals mass over volume and if the mass is greater in an object that has the same volume, then the density of the object will be greater than the other.
In this lab we will be heating up substances and use them to galvanize pennies. When you heat up the zinc, and then coat the penny in it, it then galvanizes the penny. Meaning, it helps protect the penny from oxygen and water. Afterwards, you will need to record data such as the mass of the penny. This helps keep track of what physical traits are being changed during this experiment. On part B of this experiment, you will be heating up the now galvanized pennies in order to see what reaction you get. The reaction you should receive from heating up the now zinc-covered pennies is that the pennies will change color.
In this lab, we will determine the percent composition of a modern (post-1982) penny by using a strong acid to react and dissolve the zinc core, leaving only the copper coating. Once only copper remains, we will compare its mass to the entire mass of the penny to determine how much of a penny is copper and how much is zinc.
3. The spectrophotometer was set at 420nm. Distilled water was also used as the ‘blank’.
Incorporation of assay controls included setting up a spectrophotomer and running the chart recorder with a full-scale deflection before the start of the assay. The set recorder had a corresponding value of 1 for the change in the absorbance. Therefore, prior testing was done to observe whether a change occurred in the readings. This helped to indicate that the results were valid, as they could have been affected by a fault during the setting up of the spectrophotometer. On the other hand this was considered as one of the controls for the experiment. Nevertheless, a new cuvette had to be used for each assay.
The main objective of this experiment is to carry out qualitative analysis to identify metal cations in unknown solution 1.
concentration, record the absorbance readings at a fixed wavelength, and plot the absorbance vs. concentration data. The wavelength of 520 nm was selected for experiment Part
When the zinc was added to the copper (II) sulfate solution, the solution started to bubble. As the solution was stirred, it turned a cloudy blue. Small flecks of a brown solid were visible. As the solution became colorless, the brown solid settled to the bottom of the beaker. The solid formed was copper in its elemental state. The color faded from the solution as the copper ions slowly formed into solid copper. The copper was poured into a funnel with filter paper and washed three times with 25 mL
The size of the flame depends on the gas-air mixture. If a high proportion of primary air enters the flame would be much smaller and concentrated giving higher flame temperatures. This gives rise to carbon dioxide because of unburned gases. For this the injector was again the great solution. As the gas comes out of the injector air enters into the stream and is mixed in the mixing tube with the gas before it comes out of the burner port. Combustion zone is where the gas burns in the primary air and generates heat in the flame and combustion is completed with the aid of the secondary air that is drawn into the air from the sides.