0.2500 g sample of swimming pool oxidizer containing calcium hypochlorite as the active ingredient was dissolved in 0.50 M H2SO4 containing KI. The liberated iodine required 38.2 mL of Na2S2O3. The titrant was standardized by titrating 101.3 mg K2Cr2O7 dissolved in acid with the action of excess KI, which required 17.4 mL of the Na2S2O3. Calculate the % Ca(OCl)2 in the sample.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter17: Complexation And Precipitation Reactions And Titrations
Section: Chapter Questions
Problem 17.31QAP
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A 0.2500 g sample of swimming pool oxidizer containing calcium hypochlorite as the active ingredient was dissolved in 0.50 M H2SO4 containing KI. The liberated iodine required 38.2 mL of Na2S2O3. The titrant was standardized by titrating 101.3 mg K2Cr2O7 dissolved in acid with the action of excess KI, which required 17.4 mL of the Na2S2O3. Calculate the % Ca(OCl)2 in the sample.

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