1. A 300 mole mixture that is 30.0 mol% acetic acid at 0.4 bar is compressed isothermally. At what pressure will the first vapor bubble form from this mixture? 2. The mixture in (a) is further compressed to 1.2 bar. What is the amount and composition of the liquid and/or vapor phases formed from the mixture at this pressure? 3. At what pressure will the last drop of liquid from the mixture vaporize? Note: Use a tolerance value of 1 x 10-² in calculations. Do it manually.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
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The Pxy diagram for chloroform/acetic acid system at 80 °C bar:
P (bar)
2.0
1.8
1.6
1.4
1.2
1.0
0.8
0.6
0.4
0.2
0.0
0.0
Pxy Plot for Chloroform/Acetic Acid
0.1 0.2
-x-y
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
x, y (Chloroform), mol.frac.
1. A 300 mole mixture that is 30.0 mol% acetic acid at 0.4 bar is compressed isothermally.
At what pressure will the first vapor bubble form from this mixture?
2. The mixture in (a) is further compressed to 1.2 bar. What is the amount and composition
of the liquid and/or vapor phases formed from the mixture at this pressure?
3. At what pressure will the last drop of liquid from the mixture vaporize?
Note: Use a tolerance value of 1 x 10-² in calculations. Do it manually.
Transcribed Image Text:The Pxy diagram for chloroform/acetic acid system at 80 °C bar: P (bar) 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0.6 0.4 0.2 0.0 0.0 Pxy Plot for Chloroform/Acetic Acid 0.1 0.2 -x-y 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 x, y (Chloroform), mol.frac. 1. A 300 mole mixture that is 30.0 mol% acetic acid at 0.4 bar is compressed isothermally. At what pressure will the first vapor bubble form from this mixture? 2. The mixture in (a) is further compressed to 1.2 bar. What is the amount and composition of the liquid and/or vapor phases formed from the mixture at this pressure? 3. At what pressure will the last drop of liquid from the mixture vaporize? Note: Use a tolerance value of 1 x 10-² in calculations. Do it manually.
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