1. Give the IUPAC name of each alkene. H3C CH3 H2C=CHĊHCH3 (а) (b) CH3 CH3CH2CH=ĊCH2CH3 CH3 Onl (с) CH3 CH3 (d) CH3CHCH2CH3 CH3CH2CH2CH=CHCHCH2CH3 CH3CH=CHCHCH=CHCHCH3

Organic Chemistry
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Chapter17: Alcohols And Phenols
Section17.SE: Something Extra
Problem 69AP: As a rule, axial alcohols oxidize somewhat faster than equatorial alcohols. Which would you expect...
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1. Give the IUPAC name of each alkene.
H3Ç CH3
H2C=CHĊHCH3
(a)
(Б)
CH3
CH3CH2CH=CH2CH3
ČH3
Only
(c)
CH3
CH3
(d)
CH3CHCH2CH3
CH3CH=CHCHCH=CHCHCH3
2. Give the IUPAC name of each alkyne.
CH3CH2CH2CH=CHCHCH2CH3
(a)
CH3
CH3
(b)
CH3
CH3CHC=CCHCH3
HC=CCCH3
ČH3
(c)
CH3
(d)
CH3 CH3
CH3CH2CC=CCH2CH2CH3
CH3CH2CC=CCHCH3
CH3
ČH3
3. Assign E or Z configuration to the following alkenes:
CH2OH
c=C
(a) H3C
(b)
CI
CH2CH3
c=C
CH3CH2
CI
CH30
CH2CH2CH3
4. Predict the products of the following reactions.
CH3
(a)
(Ь)
HCI
HBr
CH3C=CHCH2CH3
?
5. Draw the product/s of the reaction below and indicate their stereochemistry.
CH3.C=CH
CH3
Br2
H20
6. What product would you obtain by the hydration of 1-butyne? Show the mechanism.
7. What alkyne is formed in the reaction below?
[1] NANH2
H-C=C-H
[2] CH,Br
Transcribed Image Text:1. Give the IUPAC name of each alkene. H3Ç CH3 H2C=CHĊHCH3 (a) (Б) CH3 CH3CH2CH=CH2CH3 ČH3 Only (c) CH3 CH3 (d) CH3CHCH2CH3 CH3CH=CHCHCH=CHCHCH3 2. Give the IUPAC name of each alkyne. CH3CH2CH2CH=CHCHCH2CH3 (a) CH3 CH3 (b) CH3 CH3CHC=CCHCH3 HC=CCCH3 ČH3 (c) CH3 (d) CH3 CH3 CH3CH2CC=CCH2CH2CH3 CH3CH2CC=CCHCH3 CH3 ČH3 3. Assign E or Z configuration to the following alkenes: CH2OH c=C (a) H3C (b) CI CH2CH3 c=C CH3CH2 CI CH30 CH2CH2CH3 4. Predict the products of the following reactions. CH3 (a) (Ь) HCI HBr CH3C=CHCH2CH3 ? 5. Draw the product/s of the reaction below and indicate their stereochemistry. CH3.C=CH CH3 Br2 H20 6. What product would you obtain by the hydration of 1-butyne? Show the mechanism. 7. What alkyne is formed in the reaction below? [1] NANH2 H-C=C-H [2] CH,Br
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ISBN:
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Publisher:
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