1. Give the structure of the major product(s) in each of the following reactions. Give stereochemistry where appropriate. (a) (b) (c) Ph COOMe COOMe MCPBA (1 eq.) HCI (excess) Br₂ H₂O C B A

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution
Section16.8: Oxidation Of Aromatic Compounds
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1. Give the structure of the major product(s) in each of the following reactions. Give
stereochemistry where appropriate.
(a)
(b)
(c)
(d)
(e)
Ph
COOMe
COOMe
HCI (excess)
1-BuOK
CHC13
Br₂
H₂O
MCPBA (1 eq.)
CH₂1₂/Zn(Cu)
diethyl ether
D
(1) OsO4, pyridine, 25°C
(2) NaHSO3
C
E
B
F
→ А
Transcribed Image Text:1. Give the structure of the major product(s) in each of the following reactions. Give stereochemistry where appropriate. (a) (b) (c) (d) (e) Ph COOMe COOMe HCI (excess) 1-BuOK CHC13 Br₂ H₂O MCPBA (1 eq.) CH₂1₂/Zn(Cu) diethyl ether D (1) OsO4, pyridine, 25°C (2) NaHSO3 C E B F → А
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