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- (−)-Hyoscyamine, an optically active drug used to treat gastrointestinal disorders, is isolated from Atropa belladonna, the deadly nightshade plant, by a basic aqueous extraction procedure. If too much base is used during isolation, optically inactive material is isolated. (a) Explain this result by drawing a stepwise mechanism. (b) Explain why littorine, an isomerisolated from the tailower plant in Australia, can be obtained optically pure regardless of the amount of base used during isolation.Provide a stepwise synthesis for benzyl chloride to benzoic acid. (including arrow-pushing mechanisms) Please show all the arrow pushCompound K, L and M are three isomers with the molecular formula C5H10O.Compound K cannot be oxidized, while compound M and L can be oxidized.Oxidation of compound L with hot acidified potassium permanganate,KMnO4 solution yields 2-methylbutanoic acid. When treated with Iodoformreagent, yellow precipitation only occurs in compound K. Fehling test onlyyielded positive results for compound L and negative for compound M andK. Compound M is then reacted with hydrogen chloride, HCl produceschlorocyclopentane
- Compound K, L and M are three isomers with the molecular formula C5H10O.Compound K cannot be oxidized, while compound M and L can be oxidized.Oxidation of compound L with hot acidified potassium permanganate,KMnO4 solution yields 2-methylbutanoic acid. When treated with Iodoformreagent, yellow precipitation only occurs in compound K. Fehling test onlyyielded positive results for compound L and negative for compound M andK. Compound M is then reacted with hydrogen chloride, HCl produceschlorocyclopentane (i) Draw the structural formula of compounds K, L and M.Compound K, L and M are three isomers with the molecular formula C5H10O.Compound K cannot be oxidized, while compound M and L can be oxidized.Oxidation of compound L with hot acidified potassium permanganate,KMnO4 solution yields 2-methylbutanoic acid. When treated with Iodoformreagent, yellow precipitation only occurs in compound K. Fehling test onlyyielded positive results for compound L and negative for compound M andK. Compound M is then reacted with hydrogen chloride, HCl produceschlorocyclopentane. (ii) Name the type of chemical reaction of compound M when reacted withhydrogen chloride, HCl .Compound A has acidity stronger than compound B
- Provide a stepwise synthesis for benzyl chloride to benzoic acid. (including arrow-pushing mechanisms)For the acid-base reaction: a.) Provide structures for A and B (including nonbonding electron pairs and formal charges where necessary), where A is the conjugate acid and B is the conjugate base of the reaction. b.) Provide and arrow pushing mechanism to show how A and B are formed. c.) Will the reaction proceed from left to right (i.e. are A and B favoured at equilibrium)? Please explain your answer!!!!Compound 1 is an anticoagulant that is extracted from, among other plants, the sweetclover plant, Melilotus Officinalis. However, the compound is moderately toxic and alsofinds use as a rodenticide. Name this compound
- Rank the nitrogens in order of decreasing basicity 1, 2, and 3I want to prepare a working formulae for manufacturing a organic based body soap , for this can you make a master formulae for this? Please mention all the ingredients along with the required percentage or amount. And also mention all the step by step procedures for making this hand washing liquid. Please answer at your own easy words. I will rate you positive if you do so.Suggest curved arrow mechanism for 1 from 2 and identify compound A