1. What is the MW of the analyte?2. What is the meq of the analyte?3. What is the weight (in grams) of the analyte?4. What will be the percentage purity of the sample if 43mL of the titrant was consumed?5. Did the sample conform to the USP requirement? Yes or No? Assay of Hydrogen Peroxide SolutionProcedure:1.Pipet 2 milliliters of hydrogen peroxide solution into a suitable flask containing 20 milliliters of water. (H2O2 p = 1.45 g/ml)2.Add 20 milliliters of diluted sulfuric acid3.Titrate with 0.1 N potassium permanganate solution.Chemical reaction involved:H2O2 + KMno4 + H2SO4 02 + MnSO, + K2SO, + H20Probable atomic weights to be used:K=39H=1Mn= 55O=16S=32

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1. What is the MW of the analyte? 2. What is the meq of the analyte? 3. What is the weight (in grams) of the analyte? 4. What will be the percentage purity of the sample if 43mL of the titrant was consumed? 5. Did the sample conform to the USP requirement? Yes or No?

1. What is the MW of the analyte? 2. What is the meq of the analyte? 3. What is the weight (in grams) of the analyte? 4. What will be the percentage purity of the sample if 43mL of the titrant was consumed? 5. Did the sample conform to the USP requirement? Yes or No?

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter16: Applications Of Neutralization Titrations

Section: Chapter Questions

Problem 16.20QAP

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Sulfide ion (S2- ) is formed in wastewater by the action of an aerobic bacteria on organic matter. Sulfide can be readily protonated to form volatile, toxic H2S. In addition to the toxicity and noxious odor, sulfide and H2S cause corrosion problems because they can be easily converted to sulfuric acid when conditions change to aerobic. One common method to determine sulfide is by coulometric titration with generated silver ion.At the generator electrode, the reaction is Ag Ag+ + e-. The titration reaction is S2- + 2Ag+ Ag2S(s). (a) A digital chloridometer was used to determine the mass of sulfide in a wastewater sample. The chloridometer reads out directly in ng Cl-.In chloride determinations, the same generator reaction is used,but the titration reaction is Cl- + Ag+ AgCI(s). Derive an equation that relates the desired quantity, mass S2- (ng), to the chloridometer readout in mass Cl- (ng). (b) A particular wastewater standard gave a reading of 1689.6 ng Cl-. What total charge in coulombs was required to generate the Ag+ needed to precipitate the sulfide in this standard? (c) The following results were obtained on 20.00-mL samples containing known amounts of sulfide.17 Each standard was analyzed in triplicate and the mass of chloride recorded. Convert each of the chloride results to mass S2- (ng). (d) Determine the average mass of S2- (ng), the standard deviation, and the %RSD) of each standard. (e) Prepare a plot ofthe average mass of S2- determined (ng) versus the actual mass (ng). Determine theslope, the intercept, the standard error, and the R2 value. Comment on the fit of the data to a linear model. (f) Determine the detection limit (ng) and in parts per million using a k factor of 2 (see Equation 1-12). (g) An unknown wastewater sample gave an average reading of 893.2 ng Cl. What is the mass of sulfide (ng)? If 20.00 mL of the wastewater sample was introduced into the titration vessel, what is the concentration of S2- n parts per million?
A commercial vinegar was analyzed by titration to determine the percent acetic acid. Briefly, 10.00 mL of vinegar sample was diluted to 100. mL solution in volumetric flask. A 25.00 mL aliquot from the diluted vinegar required 25.55 mL of 0.1005 M NaOH to reach the phenolphthalein endpoint. Which is the correct equation between the analyte and titrant reaction? CH3COOH + NaOH → NaCH3COO + H2O 2CH3COOH + NaOH → NaCH3COO + H2O C20H14O4 + NaOH → NaC20H14O4 + H2O CH3COOH + 2NaOH → NaCH3COO + H2O
1. 2MnO4— + 5C2O42— + 16H+ 2Mn2+ + 10CO2 + 8H2O A solution of KMnO4 was prepared and 50.99 mL was used to completely titrate 0.5355 g of pure Na2C2O4. What is the concentration of the KMnO4 solution? Na2C2O4 = 134.00 g/mol 2. Titration of the I2 produced from 0.2645g of primary standard KIO3 required 45.36mL of sodium thiosulfate. Calculate the concentration of the Na2S2O3 in M. IO3- + 5I- + 6H+ --> 3I2 + 3H2O I2 + 2S2O32- --> 2I- + S4O62- KIO3 mw = 214.001g/mol
A sample of impure NaOH, which has been partially converted to Na2CO3 by exposure to CO2, is analyzed by titrating a 188.5 mg sample with 0.1065 M HCl. The volume required to reach phenolphtalein end point is 39.19 ml while the volume required to reach bromocresol green end point is 40.67 ml. Calculate the percentages of NaOH (MWt= 40 g/mole) and Na2CO3 (MWt=83 g/mole) in the sample.
The SO2 present in air is mainly responsible for the phenomenon of acid rain. The concentration of SO2 can be determined by titrating against a standard permanganate solution as follows: 5SO2 + 2MnO4- + 2H2O ---> 5SO42- + 2Ms2 + 4H+ Calculate the number of grams of SO2 in a sample of air if 4.90mL of 0.00700M KMnO4 solution are required for the titration. Be sure your answer has the correct number of significant digits.
A vinegar solution was prepared by diluting 25.00 mL of vinegar to 250.0 mL. From this solution, 50.00 mL portion was taken, and this required 30.00 mL of 0.1000M NaOH solution to reach neutralization end point. What is the percentage (w/v) of HOAc in the sample? Mol wt HOAc = 60.0 g/mol
A saturated solution of magnesium hydroxide is prepared and the excess solid magneisum hydorixed is allowed to settle. A 25.0 mL aliquot of the saturated solution is withdrawn and transfered to a flask, two drops of inficator are added. A 0.00053 M HCL is dispensed from a buret into a solution. The solution changes color after the addition of 13.2 mL. What is the Ksp of magnesium hydroxide?
Chemistry A 2.139 g sample of a solid mixture containing only potassium carbonate (MM=138.2058 g/mol) and potassium bicarbonate (MM=100.1154 g/mol) is dissolved in distilled water. A volume of 30.57 mL of a 0.752 M HCl standard solution is required to titrate the mixture to a bromocresol green end point. Calculate the weight percent of potassium carbonate and potassium bicarbonate in the mixture. K2CO3: ? WT% KHCO3: ? WT%.
Calcium fluoride is considered as a relatively insoluble compound and therefore lime or slakedlime has been considered as a possible material to remove excess fluoride in water of boreholesin certain parts of the country. The solubility product of CaF2 is Ksp = 3 x 10 – 11 and that ofCa(OH)2 isKsp =8x10-61. How much lime can be added to the water to remove 10 mg of F- ion per litre ofborehole water?(The atomic masses are Ca: 40.08; F: 19.00; O: 16; H: 1)
0.7050-g of pure KHP (FW = 204.2) was dissolved and titrated with 35.00mL of NaOH solution. The excess NaOH was backtitrated with 5.00mL of HCl solution. In a separate titration it was found that 30.00mL of NaOH will react with 28.00mL of HCl. Find the molarity of NaOH and HCl.
3I- + OCl- + 2H+ ----> I3- + Cl- + H2: A 25.00 ml sample of liquid bleach was diluted to 1000 ml in a graduated flask. A 25 ml portion of the diluted sample was pipetted into an Erlenmeyer flask and treated with excess KI to oxidize OCl- to Cl- and I3- was produced at the end of the reaction. The released I3 was titrated with 0.09892 M Na2S2O3 and 8.96 ml was spent to reach the turning point besides the starch indicator. What is the percent by weight/volume of NaOCl in the bleach sample? (NaOCl:74.44 g/mol)
400 g sample containing chloride ions (MW=35.45 g/mol) was dissolved in 50.0mL of distilled water. A 15.0 mL aliquot was taken, and was further diluted to 50.0 mL using distilled water. The diluted solution was then titrated using a 0.0989 M AgNO3 solution, and it consumed a total of 31.9 mL of the titrant in order to reach the end point. What is the concentration of the undiluted chloride solution? Round off to three (3) significant figures. What is the % (w/v) concentration of the undiluted chloride solution? Round off to two (2) decimal points. What is the % (w/w) of Cl- composition of the sample? Round off to two (2) decimal points.