10 mL of 1.8 M acetic acid (CH3COOH) is titrated with 1.0 M sodium hydroxide (NaOH). The titration curve is shown. What is the approximate pK₁? pK₂ = 0.5 12 108 fraction converted: 0.5 吉 6 4 2 0 At the pK₁, what fraction of the carboxyl group will have been converted to COO¯? Express your answer as a decimal, not a percent. 0 5 10 15 Volume of base (mL) 20 25
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What is the approximate p?apa?
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- Glucose-1-phosphate has a ΔG°′ value of −20.9 kJ/mol, whereas that for glucose-6-phosphate is −12.5 kJ/mol. After reviewing the molecular structures of these compounds, explain why there is such a difference in these values.Draw an approximate titration curve of glycine. Label the approximate isoelectric point of the glycine on the curve and be sure to label the axis of the graph. Pk1 is 2.35 and pk2 is 9.78 for glycine.At 39.9ºC, a solution of ethanol (XetOH = 0.9006, P * etOH = 130.4 Torr) and isooctane (P * iso = 43.9 Torr) forms a vapor phase with YetOH = 0.6667. The total pressure is 185.9 a. Calculate the activity and the activity coefficient of each component.b. Calculate the total pressure the solution would have if it were ideal.c. Comparing the ideal pressure to the actual pressure, what does this indicate about the molecular interactions?
- The ionization of p-nitrophenol is shown below (pKa = 7.0): a. Identify the weak acid and conjugate base. b. At pH 7, what are the relative concentrations of ionized and un-ionized p-nitrophenol? c. If enough concentrated hydrochloric acid is added to a solution of p-nitrophenol to lower the pH from 7 to 5, what will happen to the relative concentrations of the ionized and un-ionized forms? d. Ionized p-nitrophenol has a yellow color, while the un-ionized form is colorless. The yellow color can be measured using a spectrophotometer at 400nm. In order to determine the total amount of p-nitrophenol in a solution, would you perform the spectrophotometer reading at an acidic or basic pH? Clearly explain why? e. A solution of p-nitrophenol at pH 7.95 was found to have an A400 of 0.255 . What is the total concentration (in µM) of p-nitrophenol (ionized plus un-ionized) in the solution? The molar extinction coefficient of p-nitrophenol is 18,500 M-1cm-1 and the pKa is 7.An IV of 650cc of 5% dextrose contains how many grams of 5% dextrose?Upon examining the test results for the unknown carbohydrate from all the tests depicted in the images, what are some of the identities of the unknown carbohydrate? Is it one of the sugars from the list in the Reducing or Nonreducing sugars test? if not what carbohydrate is it?
- The pH of normal human blood is in the range of 7.35 to7.45. Compute the range of the concentration of H3O+and the range of the OH- concentration in normal blood.The iodine contained in every one mL of the 0.010 M iodine solution in the buret will react with 1.76 mg of vitamin C. (In other words, every mL of iodine solution needed for the titration indicates the presence of 1.76 mg of vitamin C in the juice sample.) If your titration used 7.11 mL of iodine solution, what mass of vitamin C is in your fruit juice sample (in milligrams, mg)? Include the unit and two decimal places in your answer.The ΔG°′ value for glucose-1-phosphate is -20.9 kJ/mol. If glucose and phosphate are both at 4.8 mM, what is the equilibrium concentration of glucose-1-phosphate?
- Are triacylglycerols : insoluble in water? very oxidized, contain-glycerol-fatty acids and spingosine, or do they possess a -1charge at 7.0 pH? can you select the true statement?What is the ratio of [isocitrate] to [citrate] under cellular conditions at 37°C?6 Concanavalin (ConA) is a 25.5KDa protein with pI of 4.7 and optical absorbance (A 0.1% 289) of 1.14. calculate the concentration of an aqueous solution of pure BSA protein with an absorbance of 0.66 at 280nm. give your answer in units of mg/ml ?