10. For each of the following pairs of metal complexes, circle the one that will most readily do an oxidative addition to the substrate shown. No discussion is necessary. A. CH3I: RhCI(CO)3 - or - IrH(CO)(PMe3)2 B. CH3I: Rh(I)(CO) {P(tert-butyl)3}2 - or - [Re(CO)3(dmpe)]¯¯ C. H2: Cp2Nb(NMe)(CH3) - or - [Rh(CO)212] D. Cl2: Mo(CO)3 {P(OMe)3}3 - or - Mo(CO)3(PMe3)3

10. For each of the following pairs of metal complexes, circle the one that will most readily do an oxidative addition to the substrate shown. No discussion is necessary. A. CH3I: RhCI(CO)3 - or - IrH(CO)(PMe3)2 B. CH3I: Rh(I)(CO) {P(tert-butyl)3}2 - or - [Re(CO)3(dmpe)]¯¯ C. H2: Cp2Nb(NMe)(CH3) - or - [Rh(CO)212] D. Cl2: Mo(CO)3 {P(OMe)3}3 - or - Mo(CO)3(PMe3)3

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter24: Catalytic Carbon-carbon Bond Formation

Section: Chapter Questions

Problem 24.21P

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